Insertion of sulfur dioxide into metal-carbon bonds of chloro(methyl)palladium complexes

Kelin Li; Ilia A. Guzei; James Darkwa

doi:10.1016/S0277-5387(02)01377-3

Insertion of sulfur dioxide into metal-carbon bonds of chloro(methyl)palladium complexes

Kelin Li, Ilia A. Guzei, James Darkwa

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Five chloro(methyl)palladium complexes (L-L)Pd(Me)Cl have been shown to react with SO₂ in solution to form S-sulfinato complexes of the formula (L-L)Pd(SO₂Me)Cl (L-L = dippf = 1, 1′-bis(diisopropylphosphino)ferrocene (2), dppf = bis(diphenylphosphino)ferrocene (3), dppe = 1,1′-bis(diphenylphosphino)ethane (4), COD (5) and (3,5-di-Bupz)₂ (6)). Compounds 5 and 6 are unstable in solution and slowly decompose. Representative crystal structures of (dippf)Pd(Me)Cl (1) and (dppf)Pd(SO₂Me)Cl (3) are reported.

Original language	English
Pages (from-to)	805-810
Number of pages	6
Journal	Polyhedron
Volume	22
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(02)01377-3
Publication status	Published - 15 Mar 2003
Externally published	Yes

Keywords

Crystal structures
Insertion
Palladium complexes
Sulfur dioxide

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(02)01377-3

Cite this

@article{fb72277b7ed649a38092629d9fb4e2a2,

title = "Insertion of sulfur dioxide into metal-carbon bonds of chloro(methyl)palladium complexes",

abstract = "Five chloro(methyl)palladium complexes (L-L)Pd(Me)Cl have been shown to react with SO2 in solution to form S-sulfinato complexes of the formula (L-L)Pd(SO2Me)Cl (L-L = dippf = 1, 1′-bis(diisopropylphosphino)ferrocene (2), dppf = bis(diphenylphosphino)ferrocene (3), dppe = 1,1′-bis(diphenylphosphino)ethane (4), COD (5) and (3,5-di-Bupz)2 (6)). Compounds 5 and 6 are unstable in solution and slowly decompose. Representative crystal structures of (dippf)Pd(Me)Cl (1) and (dppf)Pd(SO2Me)Cl (3) are reported.",

keywords = "Crystal structures, Insertion, Palladium complexes, Sulfur dioxide",

author = "Kelin Li and Guzei, {Ilia A.} and James Darkwa",

year = "2003",

month = mar,

day = "15",

doi = "10.1016/S0277-5387(02)01377-3",

language = "English",

volume = "22",

pages = "805--810",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "6",

}

TY - JOUR

T1 - Insertion of sulfur dioxide into metal-carbon bonds of chloro(methyl)palladium complexes

AU - Li, Kelin

AU - Guzei, Ilia A.

AU - Darkwa, James

PY - 2003/3/15

Y1 - 2003/3/15

N2 - Five chloro(methyl)palladium complexes (L-L)Pd(Me)Cl have been shown to react with SO2 in solution to form S-sulfinato complexes of the formula (L-L)Pd(SO2Me)Cl (L-L = dippf = 1, 1′-bis(diisopropylphosphino)ferrocene (2), dppf = bis(diphenylphosphino)ferrocene (3), dppe = 1,1′-bis(diphenylphosphino)ethane (4), COD (5) and (3,5-di-Bupz)2 (6)). Compounds 5 and 6 are unstable in solution and slowly decompose. Representative crystal structures of (dippf)Pd(Me)Cl (1) and (dppf)Pd(SO2Me)Cl (3) are reported.

AB - Five chloro(methyl)palladium complexes (L-L)Pd(Me)Cl have been shown to react with SO2 in solution to form S-sulfinato complexes of the formula (L-L)Pd(SO2Me)Cl (L-L = dippf = 1, 1′-bis(diisopropylphosphino)ferrocene (2), dppf = bis(diphenylphosphino)ferrocene (3), dppe = 1,1′-bis(diphenylphosphino)ethane (4), COD (5) and (3,5-di-Bupz)2 (6)). Compounds 5 and 6 are unstable in solution and slowly decompose. Representative crystal structures of (dippf)Pd(Me)Cl (1) and (dppf)Pd(SO2Me)Cl (3) are reported.

KW - Crystal structures

KW - Insertion

KW - Palladium complexes

KW - Sulfur dioxide

UR - http://www.scopus.com/inward/record.url?scp=0037444021&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(02)01377-3

DO - 10.1016/S0277-5387(02)01377-3

M3 - Article

AN - SCOPUS:0037444021

SN - 0277-5387

VL - 22

SP - 805

EP - 810

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

Insertion of sulfur dioxide into metal-carbon bonds of chloro(methyl)palladium complexes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this