TY - JOUR
T1 - Hydrothermal synthesis of novel MIL-100(Fe)@SBA-15 composite material with high adsorption efficiency towards dye pollutants for wastewater remediation
AU - Mahmoudi, Farzaneh
AU - Amini, Mostafa M.
AU - Sillanpää, Mika
N1 - Publisher Copyright:
© 2020 Taiwan Institute of Chemical Engineers
PY - 2020/11
Y1 - 2020/11
N2 - MIL-100(Fe)@SBA-15 (1) was synthesized as a composite material using SBA-15 and precursors of MIL-100(Fe) with the hydrothermal method. The structural characteristics, surface area, and morphology of the synthesized materials were measured by several analyses. The BET surface area increased from 797 m2 g−1 for SBA-15 to 1564 m2 g−1 for composite 1. The synthesized materials, SBA-15, MIL-100(Fe), and composite 1, were used for removal of methylene blue (MB), rhodamine B (RB), methyl orange (MO), and alizarin yellow R (AY) organic dyes from aqueous solution. Results revealed that composite 1 (25 mg) could adsorb most of the dyes with a maximum adsorption capacity of 38,32,30, and 41 mg g−1 for MB, RhB, MO, and AY solutions (50 mL,50 mg L−1), respectively. Moreover, composite 1 showed ultrafast and high adsorption efficiency to removal mixed cationic and anionic dye solutions. The isotherm, kinetic and thermodynamic studies for adsorption of MB solution with the composite 1 were evaluated and discussed thoroughly. Herein we suggest composite 1 as a novel adsorbent with high commercial potential for wastewater treatment because of easy preparation, good structure stability, and simultaneous adsorption of several dye solutions in a short time.
AB - MIL-100(Fe)@SBA-15 (1) was synthesized as a composite material using SBA-15 and precursors of MIL-100(Fe) with the hydrothermal method. The structural characteristics, surface area, and morphology of the synthesized materials were measured by several analyses. The BET surface area increased from 797 m2 g−1 for SBA-15 to 1564 m2 g−1 for composite 1. The synthesized materials, SBA-15, MIL-100(Fe), and composite 1, were used for removal of methylene blue (MB), rhodamine B (RB), methyl orange (MO), and alizarin yellow R (AY) organic dyes from aqueous solution. Results revealed that composite 1 (25 mg) could adsorb most of the dyes with a maximum adsorption capacity of 38,32,30, and 41 mg g−1 for MB, RhB, MO, and AY solutions (50 mL,50 mg L−1), respectively. Moreover, composite 1 showed ultrafast and high adsorption efficiency to removal mixed cationic and anionic dye solutions. The isotherm, kinetic and thermodynamic studies for adsorption of MB solution with the composite 1 were evaluated and discussed thoroughly. Herein we suggest composite 1 as a novel adsorbent with high commercial potential for wastewater treatment because of easy preparation, good structure stability, and simultaneous adsorption of several dye solutions in a short time.
KW - Adsorption
KW - Composite material
KW - MIL-100(Fe)
KW - Organic dyes
KW - SBA-15
UR - http://www.scopus.com/inward/record.url?scp=85097063291&partnerID=8YFLogxK
U2 - 10.1016/j.jtice.2020.11.025
DO - 10.1016/j.jtice.2020.11.025
M3 - Article
AN - SCOPUS:85097063291
SN - 1876-1070
VL - 116
SP - 303
EP - 313
JO - Journal of the Taiwan Institute of Chemical Engineers
JF - Journal of the Taiwan Institute of Chemical Engineers
ER -
