How Ionization Catalyzes Diels-Alder Reactions

Pascal Vermeeren; Trevor A. Hamlin; F. Matthias Bickelhaupt

doi:10.1002/chem.202201620

How Ionization Catalyzes Diels-Alder Reactions

Pascal Vermeeren
, Trevor A. Hamlin
, F. Matthias Bickelhaupt

Research output: Contribution to journal › Article › peer-review

Abstract

Invited for the cover of this issue are Pascal Vermeeren, Trevor A. Hamlin, and F. Matthias Bickelhaupt of the TheoCheM group at the Vrije Universiteit Amsterdam. The cover art depicts how ionizing the dienophile lowers the Diels-Alder reaction barrier between 1,3-butadiene and acrylaldehyde by reducing the destabilizing steric Pauli repulsion and enhancing the stabilizing orbital interactions. Read the full text of the article at 10.1002/chem.202200987.

Original language	English
Pages (from-to)	e202201620
Journal	Chemistry - A European Journal
Volume	28
Issue number	40
DOIs	https://doi.org/10.1002/chem.202201620
Publication status	Published - 15 Jul 2022
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Organic Chemistry

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10.1002/chem.202201620

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AB - Invited for the cover of this issue are Pascal Vermeeren, Trevor A. Hamlin, and F. Matthias Bickelhaupt of the TheoCheM group at the Vrije Universiteit Amsterdam. The cover art depicts how ionizing the dienophile lowers the Diels-Alder reaction barrier between 1,3-butadiene and acrylaldehyde by reducing the destabilizing steric Pauli repulsion and enhancing the stabilizing orbital interactions. Read the full text of the article at 10.1002/chem.202200987.

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How Ionization Catalyzes Diels-Alder Reactions

Abstract

ASJC Scopus subject areas

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