Hammett Reaction Constant for a Terminal Methylphosphinidene Complex

Jui Te Hung; Koop Lammertsma

doi:10.1021/om00060a069

Hammett Reaction Constant for a Terminal Methylphosphinidene Complex

Jui Te Hung, Koop Lammertsma

University of Alabama at Birmingham

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A Hammett reaction constant ρ ⁺ of -0.60 has been determined for the styrene addition of H₃C-P-W(C-O)₅, as generated from the appropriate 7-phosphanorbornadlene complex. The anti-l syn-phosphirane product ratio is ca. 4.

Original language	English
Pages (from-to)	4365-4366
Number of pages	2
Journal	Organometallics
Volume	11
Issue number	12
DOIs	https://doi.org/10.1021/om00060a069
Publication status	Published - 1 Dec 1992
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00060a069

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title = "Hammett Reaction Constant for a Terminal Methylphosphinidene Complex",

abstract = "A Hammett reaction constant ρ + of -0.60 has been determined for the styrene addition of H3C-P-W(C-O)5, as generated from the appropriate 7-phosphanorbornadlene complex. The anti-l syn-phosphirane product ratio is ca. 4.",

author = "Hung, {Jui Te} and Koop Lammertsma",

year = "1992",

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doi = "10.1021/om00060a069",

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AU - Hung, Jui Te

AU - Lammertsma, Koop

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N2 - A Hammett reaction constant ρ + of -0.60 has been determined for the styrene addition of H3C-P-W(C-O)5, as generated from the appropriate 7-phosphanorbornadlene complex. The anti-l syn-phosphirane product ratio is ca. 4.

AB - A Hammett reaction constant ρ + of -0.60 has been determined for the styrene addition of H3C-P-W(C-O)5, as generated from the appropriate 7-phosphanorbornadlene complex. The anti-l syn-phosphirane product ratio is ca. 4.

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U2 - 10.1021/om00060a069

DO - 10.1021/om00060a069

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EP - 4366

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Hammett Reaction Constant for a Terminal Methylphosphinidene Complex

Abstract

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