Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity

Bing Wang; Koop Lammertsma

doi:10.1021/ja00102a015

Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity

Bing Wang, Koop Lammertsma

University of Alabama at Birmingham

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The Hammett reaction constant Q⁺ has been determined for the styrene addition of MeO—P—W(CO)₅, as generated from the appropriate 7—phosphanorbomadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.

Original language	English
Pages (from-to)	10486-10488
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	116
Issue number	23
DOIs	https://doi.org/10.1021/ja00102a015
Publication status	Published - 1 Nov 1994
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Biochemistry
General Chemistry
Colloid and Surface Chemistry

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10.1021/ja00102a015

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@article{0b5535b5fdf74c96a3dd341b7b8cb95b,

title = "Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity",

abstract = "The Hammett reaction constant Q+ has been determined for the styrene addition of MeO—P—W(CO)5, as generated from the appropriate 7—phosphanorbomadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.",

author = "Bing Wang and Koop Lammertsma",

year = "1994",

month = nov,

day = "1",

doi = "10.1021/ja00102a015",

language = "English",

volume = "116",

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journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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T1 - Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity

AU - Wang, Bing

AU - Lammertsma, Koop

PY - 1994/11/1

Y1 - 1994/11/1

N2 - The Hammett reaction constant Q+ has been determined for the styrene addition of MeO—P—W(CO)5, as generated from the appropriate 7—phosphanorbomadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.

AB - The Hammett reaction constant Q+ has been determined for the styrene addition of MeO—P—W(CO)5, as generated from the appropriate 7—phosphanorbomadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.

UR - https://www.scopus.com/pages/publications/0001449713

U2 - 10.1021/ja00102a015

DO - 10.1021/ja00102a015

M3 - Article

AN - SCOPUS:0001449713

SN - 0002-7863

VL - 116

SP - 10486

EP - 10488

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Hammett Reaction Constant for a Terminal Methoxyphosphinidene Complex. Absence of Ambiphilicity

Abstract

ASJC Scopus subject areas

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