Abstract
The Hammett reaction constant Q+ has been determined for the styrene addition of MeO—P—W(CO)5, as generated from the appropriate 7—phosphanorbomadiene complex. The phosphinidene reactivity is evaluated and compared with that of the ambiphilic MeO-C-Cl carbene.
Original language | English |
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Pages (from-to) | 10486-10488 |
Number of pages | 3 |
Journal | Journal of the American Chemical Society |
Volume | 116 |
Issue number | 23 |
DOIs | |
Publication status | Published - 1 Nov 1994 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Biochemistry
- Colloid and Surface Chemistry