Green fabrication of fluorescent N-doped carbon quantum dots from Aegle marmelos leaves for highly selective detection of Fe3+ metal ions

Rishabh, Manviri Rani, Uma Shanker, Balbir Singh Kaith, Mika Sillanpää

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

This current study uses a simple, environmentally friendly, and economically advantageous Microwave method to create water-soluble carbon dots from Aegle marmelos leaves. Nitrogen-doped carbon dots (N-CQDs) that have been produced exhibit outstanding benefits such as water solubility, biocompatibility, and high stability. Essential characterization methods are used to examine it, including XRD, FTIR, HR-TEM, XPS, UV–vis, and fluorescence spectroscopy. It exhibits excitation-dependent emission behavior, blue emission under UV lamp illumination (wavelength 365 nm), and pH independence. Synthesized N-CQDs with a quantum yield of 14.21 % responded exceptionally well to Fe3+ ions, which causes fluorescence to quench. A single probe fluorescence-based system for detecting Fe3+ ions with high selectivity and sensitivity was designed. Under optimized fluorescence experimental conditions, the linear range of Fe3+ ions was 0–20 μM with a detection limit of 0.184 µM (R2 = 0.99363). The produced N-CQDs respond exceptionally well to Fe3+ ions, which causes fluorescence to quench. This study demonstrates a single probe FL-based device for detecting Fe3+ ions with high sensitivity and selectivity.

Original languageEnglish
Article number111878
JournalInorganic Chemistry Communication
Volume159
DOIs
Publication statusPublished - Jan 2024

Keywords

  • Aegle Marmelos
  • Fe ions
  • Fluorescent “turn-off” sensor
  • N-CQDs
  • Selective detection

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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