Functionalization of P4 in the coordination sphere of coinage metal cations

Jaap E. Borger; Martijn S. Bakker; Andreas W. Ehlers; Martin Lutz; J. Chris Slootweg; Koop Lammertsma

doi:10.1039/c5cc10037b

Functionalization of P₄ in the coordination sphere of coinage metal cations

Jaap E. Borger, Martijn S. Bakker, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Koop Lammertsma

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η²-P₄ complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes₂C₆H₃) and the unencumbered MesLi, giving sterically diverse doubly complexed RP₄ butterfly derivatives in a single step.

Original language	English
Pages (from-to)	3284-3287
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	16
DOIs	https://doi.org/10.1039/c5cc10037b
Publication status	Published - 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc10037b

Cite this

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abstract = "Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2-P4 complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.",

author = "Borger, {Jaap E.} and Bakker, {Martijn S.} and Ehlers, {Andreas W.} and Martin Lutz and Slootweg, {J. Chris} and Koop Lammertsma",

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T1 - Functionalization of P4 in the coordination sphere of coinage metal cations

AU - Borger, Jaap E.

AU - Bakker, Martijn S.

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

PY - 2016

Y1 - 2016

N2 - Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2-P4 complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.

AB - Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η2-P4 complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.

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U2 - 10.1039/c5cc10037b

DO - 10.1039/c5cc10037b

M3 - Article

AN - SCOPUS:84958817758

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SP - 3284

EP - 3287

JO - Chemical Communications

JF - Chemical Communications

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ER -

Functionalization of P₄ in the coordination sphere of coinage metal cations

Abstract

ASJC Scopus subject areas

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