Abstract
Methoxy-polyethylene glycol (MPEG)-doped Cu (I)-polyaniline acts as an efficient catalyst for the 1,2,3-triazole formation reaction. The catalyst shows excellent performance when the reaction was carried out under ultraviolet irradiation conditions due to the photo-induced free-radical formation from the MPEG. A detailed mechanistic discussion on the free-radical generation, free-radical-mediated hydrogen abstraction and triazole formation has been outlined in this manuscript. The catalyst system is equally active for one-pot multi-component strategies for the title reaction.
Original language | English |
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Article number | e4733 |
Journal | Applied Organometallic Chemistry |
Volume | 33 |
Issue number | 4 |
DOIs | |
Publication status | Published - Apr 2019 |
Keywords
- Cu (I) catalyst
- free-radical
- triazole formation
- ultraviolet irradiation
ASJC Scopus subject areas
- General Chemistry
- Inorganic Chemistry