(Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP) gold(I) dichloro-methane monosolvate

Hendriette Van Der Walt; Alfred Muller; Richard J. Staples; Werner E. Van Zyl

doi:10.1107/S1600536810039255

(Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP) gold(I) dichloro-methane monosolvate

Hendriette Van Der Walt, Alfred Muller, Richard J. Staples, Werner E. Van Zyl

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [AuFe(C₅H₅)(C ₅H₅O₂PS)(C₁₈H₁₅P)] ·CH₂Cl₂, the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P - Au - S bond angle of 176.81 (6)°. The difference in P=O and P - O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P - O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link dinuclear mol-ecules into chains propagated in the [010] direction. The dichloro-methane solvent mol-ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.

Original language	English
Pages (from-to)	m1364-m1365
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S1600536810039255
Publication status	Published - Nov 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP) gold(I) dichloro-methane monosolvate",

abstract = "In the title compound, [AuFe(C5H5)(C 5H5O2PS)(C18H15P)] ·CH2Cl2, the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P - Au - S bond angle of 176.81 (6)°. The difference in P=O and P - O(H) bond lengths, which are 1.503 (6) and 1.541 (5) {\AA}, respectively, implies there is apparently no delocalization between the P - O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link dinuclear mol-ecules into chains propagated in the [010] direction. The dichloro-methane solvent mol-ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.",

author = "{Van Der Walt}, Hendriette and Alfred Muller and Staples, {Richard J.} and {Van Zyl}, {Werner E.}",

year = "2010",

month = nov,

doi = "10.1107/S1600536810039255",

language = "English",

volume = "66",

pages = "m1364--m1365",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

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TY - JOUR

T1 - (Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP) gold(I) dichloro-methane monosolvate

AU - Van Der Walt, Hendriette

AU - Muller, Alfred

AU - Staples, Richard J.

AU - Van Zyl, Werner E.

PY - 2010/11

Y1 - 2010/11

N2 - In the title compound, [AuFe(C5H5)(C 5H5O2PS)(C18H15P)] ·CH2Cl2, the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P - Au - S bond angle of 176.81 (6)°. The difference in P=O and P - O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P - O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link dinuclear mol-ecules into chains propagated in the [010] direction. The dichloro-methane solvent mol-ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.

AB - In the title compound, [AuFe(C5H5)(C 5H5O2PS)(C18H15P)] ·CH2Cl2, the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P - Au - S bond angle of 176.81 (6)°. The difference in P=O and P - O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P - O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link dinuclear mol-ecules into chains propagated in the [010] direction. The dichloro-methane solvent mol-ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.

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U2 - 10.1107/S1600536810039255

DO - 10.1107/S1600536810039255

M3 - Article

AN - SCOPUS:78650941005

SN - 1600-5368

VL - 66

SP - m1364-m1365

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

(Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP) gold(I) dichloro-methane monosolvate

Abstract

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