Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3-

Hendrik J. van der Westhuizen; Andreas Roodt; Reinout Meijboom

doi:10.1016/j.poly.2009.06.030

Equilibrium and kinetic studies of reactions of [MnN(H₂O)(CN)₄]^2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)₄]^3-

Hendrik J. van der Westhuizen
, Andreas Roodt
, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The dissolution of [(CH₃)N]₂Na[MnN(CN)₅]·H₂O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H₂O)(CN)₄]^2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS^- and N₃^-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H₂O)(CN)₄]^2- in solution.

Original language	English
Pages (from-to)	470-476
Number of pages	7
Journal	Polyhedron
Volume	29
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2009.06.030
Publication status	Published - 13 Jan 2010

Keywords

Kinetics
Manganese
Nitrido complex
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2009.06.030

Cite this

@article{75c1dbd4d3a74cc7b7e76ba1797a1584,

title = "Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3-",

abstract = "The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.",

keywords = "Kinetics, Manganese, Nitrido complex, X-ray structure",

author = "\{van der Westhuizen\}, \{Hendrik J.\} and Andreas Roodt and Reinout Meijboom",

year = "2010",

month = jan,

day = "13",

doi = "10.1016/j.poly.2009.06.030",

language = "English",

volume = "29",

pages = "470--476",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "1",

}

TY - JOUR

T1 - Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3-

AU - van der Westhuizen, Hendrik J.

AU - Roodt, Andreas

AU - Meijboom, Reinout

PY - 2010/1/13

Y1 - 2010/1/13

N2 - The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.

AB - The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.

KW - Kinetics

KW - Manganese

KW - Nitrido complex

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/78549260910

U2 - 10.1016/j.poly.2009.06.030

DO - 10.1016/j.poly.2009.06.030

M3 - Article

AN - SCOPUS:78549260910

SN - 0277-5387

VL - 29

SP - 470

EP - 476

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -