Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3-

Hendrik J. van der Westhuizen; Andreas Roodt; Reinout Meijboom

doi:10.1016/j.poly.2009.06.030

Equilibrium and kinetic studies of reactions of [MnN(H₂O)(CN)₄]^2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)₄]^3-

Hendrik J. van der Westhuizen, Andreas Roodt, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The dissolution of [(CH₃)N]₂Na[MnN(CN)₅]·H₂O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H₂O)(CN)₄]^2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS^- and N₃^-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H₂O)(CN)₄]^2- in solution.

Original language	English
Pages (from-to)	470-476
Number of pages	7
Journal	Polyhedron
Volume	29
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2009.06.030
Publication status	Published - 13 Jan 2010

Keywords

Kinetics
Manganese
Nitrido complex
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2009.06.030

Cite this

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abstract = "The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.",

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T1 - Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2- with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3-

AU - van der Westhuizen, Hendrik J.

AU - Roodt, Andreas

AU - Meijboom, Reinout

PY - 2010/1/13

Y1 - 2010/1/13

N2 - The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.

AB - The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2-(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS- and N3-. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2- in solution.

KW - Kinetics

KW - Manganese

KW - Nitrido complex

KW - X-ray structure

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U2 - 10.1016/j.poly.2009.06.030

DO - 10.1016/j.poly.2009.06.030

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SP - 470

EP - 476

JO - Polyhedron

JF - Polyhedron

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