Epoxy-lmide resins from N-(4- And 3-carboxyphenyl) trimellitimides: Modified with reactive rubbers

Ginu Abraham; S. Packirisamy; R. Ramaswamy; Sabu Thomas

doi:10.1080/009140390894120

Epoxy-lmide resins from N-(4- And 3-carboxyphenyl) trimellitimides: Modified with reactive rubbers

Ginu Abraham
, S. Packirisamy
, R. Ramaswamy
, Sabu Thomas

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Epoxy-imide resins obtained through the reaction of epoxy resins such as Araldite® GY 250/Araldite® EPN 1138 with N-(4- and 3-carboxyphenyl) trimellitimides (IDA-I and IDA-II, respectively) have been modified with 10wt% of epoxidized hydroxyl-terminated polybutadiene (EHTPB), 10 phr of carboxyl-terminated butadiene-acrylonitrile liquid copolymer (CTBN-L), and 10 phr of carboxyl-terminated butadiene-acrylonitrile solid copolymer (CTBN-S) without sacrificing much of their performance at elevated temperatures. Adhesive lap shear strength on stainless steel substrate at room temperature and at 100, 125, and 150©C has been evaluated for the modified and unmodified systems. CTBN-S offers a remarkable increase of 13 MPa and 8MPa in the room temperature adhesive strength of GY 250-based system and EPN 1138-based system, respectively. EHTPB gives only a marginal improvement and CTBN-L offers an improvement by 4 MPa for GY 250-based system whereas CTBN-L reduces the adhesive strength of EPN 1138-based system.

Original language	English
Pages (from-to)	1107-1132
Number of pages	26
Journal	International Journal of Polymeric Materials and Polymeric Biomaterials
Volume	54
Issue number	12
DOIs	https://doi.org/10.1080/009140390894120
Publication status	Published - Dec 2005
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Polymers and Plastics

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/009140390894120

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title = "Epoxy-lmide resins from N-(4- And 3-carboxyphenyl) trimellitimides: Modified with reactive rubbers",

abstract = "Epoxy-imide resins obtained through the reaction of epoxy resins such as Araldite{\textregistered} GY 250/Araldite{\textregistered} EPN 1138 with N-(4- and 3-carboxyphenyl) trimellitimides (IDA-I and IDA-II, respectively) have been modified with 10wt\% of epoxidized hydroxyl-terminated polybutadiene (EHTPB), 10 phr of carboxyl-terminated butadiene-acrylonitrile liquid copolymer (CTBN-L), and 10 phr of carboxyl-terminated butadiene-acrylonitrile solid copolymer (CTBN-S) without sacrificing much of their performance at elevated temperatures. Adhesive lap shear strength on stainless steel substrate at room temperature and at 100, 125, and 150{\textcopyright}C has been evaluated for the modified and unmodified systems. CTBN-S offers a remarkable increase of 13 MPa and 8MPa in the room temperature adhesive strength of GY 250-based system and EPN 1138-based system, respectively. EHTPB gives only a marginal improvement and CTBN-L offers an improvement by 4 MPa for GY 250-based system whereas CTBN-L reduces the adhesive strength of EPN 1138-based system.",

author = "Ginu Abraham and S. Packirisamy and R. Ramaswamy and Sabu Thomas",

year = "2005",

month = dec,

doi = "10.1080/009140390894120",

language = "English",

volume = "54",

pages = "1107--1132",

journal = "International Journal of Polymeric Materials and Polymeric Biomaterials",

issn = "0091-4037",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - Epoxy-lmide resins from N-(4- And 3-carboxyphenyl) trimellitimides

T2 - Modified with reactive rubbers

AU - Abraham, Ginu

AU - Packirisamy, S.

AU - Ramaswamy, R.

AU - Thomas, Sabu

PY - 2005/12

Y1 - 2005/12

N2 - Epoxy-imide resins obtained through the reaction of epoxy resins such as Araldite® GY 250/Araldite® EPN 1138 with N-(4- and 3-carboxyphenyl) trimellitimides (IDA-I and IDA-II, respectively) have been modified with 10wt% of epoxidized hydroxyl-terminated polybutadiene (EHTPB), 10 phr of carboxyl-terminated butadiene-acrylonitrile liquid copolymer (CTBN-L), and 10 phr of carboxyl-terminated butadiene-acrylonitrile solid copolymer (CTBN-S) without sacrificing much of their performance at elevated temperatures. Adhesive lap shear strength on stainless steel substrate at room temperature and at 100, 125, and 150©C has been evaluated for the modified and unmodified systems. CTBN-S offers a remarkable increase of 13 MPa and 8MPa in the room temperature adhesive strength of GY 250-based system and EPN 1138-based system, respectively. EHTPB gives only a marginal improvement and CTBN-L offers an improvement by 4 MPa for GY 250-based system whereas CTBN-L reduces the adhesive strength of EPN 1138-based system.

AB - Epoxy-imide resins obtained through the reaction of epoxy resins such as Araldite® GY 250/Araldite® EPN 1138 with N-(4- and 3-carboxyphenyl) trimellitimides (IDA-I and IDA-II, respectively) have been modified with 10wt% of epoxidized hydroxyl-terminated polybutadiene (EHTPB), 10 phr of carboxyl-terminated butadiene-acrylonitrile liquid copolymer (CTBN-L), and 10 phr of carboxyl-terminated butadiene-acrylonitrile solid copolymer (CTBN-S) without sacrificing much of their performance at elevated temperatures. Adhesive lap shear strength on stainless steel substrate at room temperature and at 100, 125, and 150©C has been evaluated for the modified and unmodified systems. CTBN-S offers a remarkable increase of 13 MPa and 8MPa in the room temperature adhesive strength of GY 250-based system and EPN 1138-based system, respectively. EHTPB gives only a marginal improvement and CTBN-L offers an improvement by 4 MPa for GY 250-based system whereas CTBN-L reduces the adhesive strength of EPN 1138-based system.

UR - https://www.scopus.com/pages/publications/27944469079

U2 - 10.1080/009140390894120

DO - 10.1080/009140390894120

M3 - Article

AN - SCOPUS:27944469079

SN - 0091-4037

VL - 54

SP - 1107

EP - 1132

JO - International Journal of Polymeric Materials and Polymeric Biomaterials

JF - International Journal of Polymeric Materials and Polymeric Biomaterials

IS - 12

ER -

Epoxy-lmide resins from N-(4- And 3-carboxyphenyl) trimellitimides: Modified with reactive rubbers

Abstract

ASJC Scopus subject areas

UN SDGs

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