Electro-Fenton and photoelectro-Fenton degradation of sulfamethazine using an active gas diffusion electrode without aeration

A novel superhydrophobic gas diffusion electrode based on carbon black (CB)- polytetrafluoroethylene (PTFE) modified graphite felt cathode was prepared to increase oxygen mass transfer efficiency and produce hydrogen peroxide at the gas-liquid-solid three-phase interface without aeration. The gas diffusion electrode system was further tested for the degradation of sulfamethazine (SMT) by electro-Fenton (EF) and photoelectro-Fenton (PEF). In the EF process, SMT was removed effectively, but the mineralization degree was not high due to the generation of organic acids which were difficult to be further degraded. While in the PEF process, organic contaminant can be destroyed by the combined action of Fe²⁺/H₂O₂, UV/H₂O₂ and UV radiation, and more efficient mineralization (>83.5%) at low current (50 mA) was attained, which might be attributed to the high H₂O₂ utilization (70–90%), rapid regeneration of Fe²⁺ and photolysis of intermediates. In addition, it was verified that the PEF system had a good adaptability to pH and pollutant concentration. Compared with aeration system, the use of this active gas diffusion cathode in electrochemical advanced oxidation processes significantly reduced energy consumption.