Dichloro({N-[2-(diphenylphosphino-κP)benzyl]-benzylamino} diphenylphosphine-κP)palladium(II) toluene solvate

Marié Pretorias; D. Bradley G. Williams; Andreas Roodt; Alfred Muller

doi:10.1107/S1600536804022214

Dichloro({N-[2-(diphenylphosphino-κP)benzyl]-benzylamino} diphenylphosphine-κP)palladium(II) toluene solvate

Marié Pretorias, D. Bradley G. Williams, Andreas Roodt, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [PdCl₂(C₃₈H₃₃NP ₂)]·C₇H₈, crystallizes with an accompanying toluene solvent molecule. Important geometrical parameters are Pd-P = 2.2556 (8) and 2.2749 (8) Å, Pd-Cl = 2.3521 (9) and 2.3338 (8) Å, P-Pd-P = 96.31 (3)°, and Cl-Pd-Cl = 89.59 (3)°.

Original language	English
Pages (from-to)	m1439-m1441
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	10
DOIs	https://doi.org/10.1107/S1600536804022214
Publication status	Published - Oct 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{7602dc54175144db8887cf8abd8e4ebe,

title = "Dichloro(\{N-[2-(diphenylphosphino-κP)benzyl]-benzylamino\} diphenylphosphine-κP)palladium(II) toluene solvate",

abstract = "The title compound, [PdCl2(C38H33NP 2)]·C7H8, crystallizes with an accompanying toluene solvent molecule. Important geometrical parameters are Pd-P = 2.2556 (8) and 2.2749 (8) {\AA}, Pd-Cl = 2.3521 (9) and 2.3338 (8) {\AA}, P-Pd-P = 96.31 (3)°, and Cl-Pd-Cl = 89.59 (3)°.",

author = "Mari{\'e} Pretorias and Williams, \{D. Bradley G.\} and Andreas Roodt and Alfred Muller",

year = "2004",

month = oct,

doi = "10.1107/S1600536804022214",

language = "English",

volume = "60",

pages = "m1439--m1441",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

}

TY - JOUR

T1 - Dichloro({N-[2-(diphenylphosphino-κP)benzyl]-benzylamino} diphenylphosphine-κP)palladium(II) toluene solvate

AU - Pretorias, Marié

AU - Williams, D. Bradley G.

AU - Roodt, Andreas

AU - Muller, Alfred

PY - 2004/10

Y1 - 2004/10

N2 - The title compound, [PdCl2(C38H33NP 2)]·C7H8, crystallizes with an accompanying toluene solvent molecule. Important geometrical parameters are Pd-P = 2.2556 (8) and 2.2749 (8) Å, Pd-Cl = 2.3521 (9) and 2.3338 (8) Å, P-Pd-P = 96.31 (3)°, and Cl-Pd-Cl = 89.59 (3)°.

AB - The title compound, [PdCl2(C38H33NP 2)]·C7H8, crystallizes with an accompanying toluene solvent molecule. Important geometrical parameters are Pd-P = 2.2556 (8) and 2.2749 (8) Å, Pd-Cl = 2.3521 (9) and 2.3338 (8) Å, P-Pd-P = 96.31 (3)°, and Cl-Pd-Cl = 89.59 (3)°.

UR - https://www.scopus.com/pages/publications/18444396612

U2 - 10.1107/S1600536804022214

DO - 10.1107/S1600536804022214

M3 - Article

AN - SCOPUS:18444396612

SN - 1600-5368

VL - 60

SP - m1439-m1441

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Dichloro({N-[2-(diphenylphosphino-κP)benzyl]-benzylamino} diphenylphosphine-κP)palladium(II) toluene solvate

Abstract

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