Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate

Ilia A. Guzei; Stephen O. Ojwach; James Darkwa

doi:10.1107/S1600536805020520

Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate

Ilia A. Guzei, Stephen O. Ojwach, James Darkwa

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Reaction of the Pd complex [(3,5-Me₂pz-CO-furan) ₂PdCl₂] (where pzH is pyrazole) and the Lewis acid B(C₆F₅)₃ in the presence of adventitious water resulted in the formation of the title compound, [PdCl₂(C ₁₀H₁₀N₂O₂)₂] ·2C₁₈HBF₁₅O₂· 2H ₂O·2CH₂C1₂, in 60% yield. The Pd complex occupies a crystallographic inversion center and exhibits a square-planar geometry. The two proposed dichloromethane molecules in the formula are highly disordered.

Original language	English
Pages (from-to)	m1492-m1494
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	8
DOIs	https://doi.org/10.1107/S1600536805020520
Publication status	Published - 1 Aug 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate",

abstract = "Reaction of the Pd complex [(3,5-Me2pz-CO-furan) 2PdCl2] (where pzH is pyrazole) and the Lewis acid B(C6F5)3 in the presence of adventitious water resulted in the formation of the title compound, [PdCl2(C 10H10N2O2)2] ·2C18HBF15O2· 2H 2O·2CH2C12, in 60% yield. The Pd complex occupies a crystallographic inversion center and exhibits a square-planar geometry. The two proposed dichloromethane molecules in the formula are highly disordered.",

author = "Guzei, {Ilia A.} and Ojwach, {Stephen O.} and James Darkwa",

year = "2005",

month = aug,

day = "1",

doi = "10.1107/S1600536805020520",

language = "English",

volume = "61",

pages = "m1492--m1494",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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}

Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate. / Guzei, Ilia A.; Ojwach, Stephen O.; Darkwa, James.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 8, 01.08.2005, p. m1492-m1494.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate

AU - Guzei, Ilia A.

AU - Ojwach, Stephen O.

AU - Darkwa, James

PY - 2005/8/1

Y1 - 2005/8/1

N2 - Reaction of the Pd complex [(3,5-Me2pz-CO-furan) 2PdCl2] (where pzH is pyrazole) and the Lewis acid B(C6F5)3 in the presence of adventitious water resulted in the formation of the title compound, [PdCl2(C 10H10N2O2)2] ·2C18HBF15O2· 2H 2O·2CH2C12, in 60% yield. The Pd complex occupies a crystallographic inversion center and exhibits a square-planar geometry. The two proposed dichloromethane molecules in the formula are highly disordered.

AB - Reaction of the Pd complex [(3,5-Me2pz-CO-furan) 2PdCl2] (where pzH is pyrazole) and the Lewis acid B(C6F5)3 in the presence of adventitious water resulted in the formation of the title compound, [PdCl2(C 10H10N2O2)2] ·2C18HBF15O2· 2H 2O·2CH2C12, in 60% yield. The Pd complex occupies a crystallographic inversion center and exhibits a square-planar geometry. The two proposed dichloromethane molecules in the formula are highly disordered.

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U2 - 10.1107/S1600536805020520

DO - 10.1107/S1600536805020520

M3 - Article

AN - SCOPUS:32244447406

SN - 1600-5368

VL - 61

SP - m1492-m1494

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)-furan]palladium(II) bis[aquatris(pentafluorophenyl)-boron] dihydrate dichloromethane disolvate

Abstract

ASJC Scopus subject areas

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