Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline- κ2P,N}platinum(II)

Haleden Chiririwa; Reinout Meijboom

doi:10.1107/S1600536811040098

Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline- κ²P,N}platinum(II)

Haleden Chiririwa, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [PtCl₂(C₃₁H₃₂NP)], is a Pt^II complex with an NPCl₂ coordination sphere in which the Pt^II atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P - Pt - N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

Original language	English
Pages (from-to)	m1496
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	11
DOIs	https://doi.org/10.1107/S1600536811040098
Publication status	Published - Nov 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline- κ2P,N}platinum(II)",

abstract = "The title compound, [PtCl2(C31H32NP)], is a PtII complex with an NPCl2 coordination sphere in which the PtII atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P - Pt - N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.",

author = "Haleden Chiririwa and Reinout Meijboom",

year = "2011",

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doi = "10.1107/S1600536811040098",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline- κ2P,N}platinum(II)

AU - Chiririwa, Haleden

AU - Meijboom, Reinout

PY - 2011/11

Y1 - 2011/11

N2 - The title compound, [PtCl2(C31H32NP)], is a PtII complex with an NPCl2 coordination sphere in which the PtII atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P - Pt - N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

AB - The title compound, [PtCl2(C31H32NP)], is a PtII complex with an NPCl2 coordination sphere in which the PtII atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P - Pt - N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

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U2 - 10.1107/S1600536811040098

DO - 10.1107/S1600536811040098

M3 - Article

AN - SCOPUS:84455183749

SN - 1600-5368

VL - 67

SP - m1496

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline- κ²P,N}platinum(II)

Abstract

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