Dichlorido{N-[2-(diphenylphosphanyl)-benzylidene]isopropylamine- κ2N,P}-palladium(II) dimethyl sulfoxide monosolvate

Haleden Chiririwa; Reinout Meijboom; Bernard Omondi

doi:10.1107/S1600536811013936

Dichlorido{N-[2-(diphenylphosphanyl)-benzylidene]isopropylamine- κ²N,P}-palladium(II) dimethyl sulfoxide monosolvate

Haleden Chiririwa, Reinout Meijboom, Bernard Omondi

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In the title Pd^II complex, [PdCl₂(C ₂₂H₂₂NP)]·(CH₃)₂SO, the Pd^II atom is coordinated in an NPCl₂ coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl̄ ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C-H⋯O interaction. The crystal structure is further stabilized through two intermolecular C-H⋯π interactions.

Original language	English
Pages (from-to)	m608-m609
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	5
DOIs	https://doi.org/10.1107/S1600536811013936
Publication status	Published - May 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811013936

Cite this

@article{3176b6f349b049fb85916d363704dbe9,

title = "Dichlorido{N-[2-(diphenylphosphanyl)-benzylidene]isopropylamine- κ2N,P}-palladium(II) dimethyl sulfoxide monosolvate",

abstract = "In the title PdII complex, [PdCl2(C 22H22NP)]·(CH3)2SO, the PdII atom is coordinated in an NPCl2 coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two C{\=l} ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) {\AA}, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C-H⋯O interaction. The crystal structure is further stabilized through two intermolecular C-H⋯π interactions.",

author = "Haleden Chiririwa and Reinout Meijboom and Bernard Omondi",

year = "2011",

month = may,

doi = "10.1107/S1600536811013936",

language = "English",

volume = "67",

pages = "m608--m609",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "5",

}

TY - JOUR

T1 - Dichlorido{N-[2-(diphenylphosphanyl)-benzylidene]isopropylamine- κ2N,P}-palladium(II) dimethyl sulfoxide monosolvate

AU - Chiririwa, Haleden

AU - Meijboom, Reinout

AU - Omondi, Bernard

PY - 2011/5

Y1 - 2011/5

N2 - In the title PdII complex, [PdCl2(C 22H22NP)]·(CH3)2SO, the PdII atom is coordinated in an NPCl2 coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl̄ ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C-H⋯O interaction. The crystal structure is further stabilized through two intermolecular C-H⋯π interactions.

AB - In the title PdII complex, [PdCl2(C 22H22NP)]·(CH3)2SO, the PdII atom is coordinated in an NPCl2 coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl̄ ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent molecules form centrosymmetric dimers due to an intermolecular C-H⋯O interaction. The crystal structure is further stabilized through two intermolecular C-H⋯π interactions.

UR - http://www.scopus.com/inward/record.url?scp=79955581603&partnerID=8YFLogxK

U2 - 10.1107/S1600536811013936

DO - 10.1107/S1600536811013936

M3 - Article

AN - SCOPUS:79955581603

SN - 1600-5368

VL - 67

SP - m608-m609

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Dichlorido{N-[2-(diphenylphosphanyl)-benzylidene]isopropylamine- κ²N,P}-palladium(II) dimethyl sulfoxide monosolvate

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this