Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl) (o-tol-yl)methanone]palladium(II)

Simphiwe M. Nelana; Gert J. Kruger; James Darkwa

doi:10.1107/S1600536807066627

Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl) (o-tol-yl)methanone]palladium(II)

Simphiwe M. Nelana
, Gert J. Kruger
, James Darkwa

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd - N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N - H⋯Cl linkages.

Original language	English
Pages (from-to)	m206-m207
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	1
DOIs	https://doi.org/10.1107/S1600536807066627
Publication status	Published - 2008

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl) (o-tol-yl)methanone]palladium(II)",

abstract = "In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd - N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N - H⋯Cl linkages.",

author = "Nelana, \{Simphiwe M.\} and Kruger, \{Gert J.\} and James Darkwa",

year = "2008",

doi = "10.1107/S1600536807066627",

language = "English",

volume = "64",

pages = "m206--m207",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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number = "1",

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T1 - Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl) (o-tol-yl)methanone]palladium(II)

AU - Nelana, Simphiwe M.

AU - Kruger, Gert J.

AU - Darkwa, James

PY - 2008

Y1 - 2008

N2 - In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd - N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N - H⋯Cl linkages.

AB - In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd - N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N - H⋯Cl linkages.

UR - https://www.scopus.com/pages/publications/38049018717

U2 - 10.1107/S1600536807066627

DO - 10.1107/S1600536807066627

M3 - Article

AN - SCOPUS:38049018717

SN - 1600-5368

VL - 64

SP - m206-m207

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl) (o-tol-yl)methanone]palladium(II)

Abstract

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