Dichlorido{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N 2)meth-yl] pyridine-N}palladium(II)

Lara C. Spencer; Ilia A. Guzei; Tebogo V. Segapelo; James Darkwa

doi:10.1107/S0108270112043119

Dichlorido{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N ²)meth-yl] pyridine-N}palladium(II)

Lara C. Spencer, Ilia A. Guzei, Tebogo V. Segapelo, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.

Original language	English
Pages (from-to)	m317-m319
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	68
Issue number	11
DOIs	https://doi.org/10.1107/S0108270112043119
Publication status	Published - Nov 2012

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

Access to Document

10.1107/S0108270112043119

Cite this

@article{2544bce9d94042649f13803c2d104bf8,

title = "Dichlorido\{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N 2)meth-yl] pyridine-N\}palladium(II)",

abstract = "The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.",

author = "Spencer, \{Lara C.\} and Guzei, \{Ilia A.\} and Segapelo, \{Tebogo V.\} and James Darkwa",

year = "2012",

month = nov,

doi = "10.1107/S0108270112043119",

language = "English",

volume = "68",

pages = "m317--m319",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Dichlorido{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N 2)meth-yl] pyridine-N}palladium(II)

AU - Spencer, Lara C.

AU - Guzei, Ilia A.

AU - Segapelo, Tebogo V.

AU - Darkwa, James

PY - 2012/11

Y1 - 2012/11

N2 - The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.

AB - The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.

UR - https://www.scopus.com/pages/publications/84869003741

U2 - 10.1107/S0108270112043119

DO - 10.1107/S0108270112043119

M3 - Article

C2 - 23124452

AN - SCOPUS:84869003741

SN - 0108-2701

VL - 68

SP - m317-m319

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Dichlorido{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N ²)meth-yl] pyridine-N}palladium(II)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this