TY - JOUR
T1 - Dichlorido{2-[(3,5-diphenyl-1H-pyra-zol-1-yl-N 2)meth-yl] pyridine-N}palladium(II)
AU - Spencer, Lara C.
AU - Guzei, Ilia A.
AU - Segapelo, Tebogo V.
AU - Darkwa, James
PY - 2012/11
Y1 - 2012/11
N2 - The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.
AB - The title compound, [PdCl2(C21H17N3)], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmeth-yl) pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmeth-yl)pyridine ligands and the Pd - Npyrazole distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd - Npyridine bond lengths.
UR - http://www.scopus.com/inward/record.url?scp=84869003741&partnerID=8YFLogxK
U2 - 10.1107/S0108270112043119
DO - 10.1107/S0108270112043119
M3 - Article
C2 - 23124452
AN - SCOPUS:84869003741
SN - 0108-2701
VL - 68
SP - m317-m319
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 11
ER -