Di-μ2-chloro-bis[(benzyldiphenylphosphine) -chloropalladium(II)]

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3 Citations (Scopus)

Abstract

The molecule of the title compound, [Pd2Cl4(C 19H17P)2] or [Pd(μ2-Cl) Cl(PPh2Bz)]2, where Bz = CH2Ph, lies on an inversion centre. The Pd atom has a distorted square-planar coordination environment formed by a benzyldiphenylphosphine [Pd-P = 2.2218 (6) Å], a terminal chloride [Pd-Cl = 2.2729 (5) Å] and two bridging chloride ligands. The Pd-Cl bond in the position trans to the phosphine ligand [Pd-Cl = 2.4123 (5) Å] is considerably longer than the Pd-Cl bond in the position trans to the terminal chloride [Pd-Cl = 2.3155 (5) Å].

Original languageEnglish
Pages (from-to)m897-m899
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number4
DOIs
Publication statusPublished - 1 Apr 2006
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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