Di -μ- thiocyanato-bis[bis(tri-p-tolyl-phosphine)silver(I)] acetonitrile disolvate

Gertruida J.S. Venter; Reinout Meijboom; Andreas Roodt

doi:10.1107/S1600536807058837

Di -μ- thiocyanato-bis[bis(tri-p-tolyl-phosphine)silver(I)] acetonitrile disolvate

Gertruida J.S. Venter, Reinout Meijboom, Andreas Roodt

University of The Free State

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

In the centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The Ag - P bond distances are 2.4615 (7) and 2.5091 (7) Å, while the Ag - N and the Ag - S bond distances are 2.364 (2) and 2.3269 (18) Å, respectively. The crystal structure exhibits C - H⋯S hydrogen bonds.

Original language	English
Pages (from-to)	m3076-m3077
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	12
DOIs	https://doi.org/10.1107/S1600536807058837
Publication status	Published - 9 Nov 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{b9c3550ebdcd4b258375dd6073ed30e3,

title = "Di -μ- thiocyanato-bis[bis(tri-p-tolyl-phosphine)silver(I)] acetonitrile disolvate",

abstract = "In the centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The Ag - P bond distances are 2.4615 (7) and 2.5091 (7) {\AA}, while the Ag - N and the Ag - S bond distances are 2.364 (2) and 2.3269 (18) {\AA}, respectively. The crystal structure exhibits C - H⋯S hydrogen bonds.",

author = "Venter, {Gertruida J.S.} and Reinout Meijboom and Andreas Roodt",

year = "2007",

month = nov,

day = "9",

doi = "10.1107/S1600536807058837",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Di -μ- thiocyanato-bis[bis(tri-p-tolyl-phosphine)silver(I)] acetonitrile disolvate

AU - Venter, Gertruida J.S.

AU - Meijboom, Reinout

AU - Roodt, Andreas

PY - 2007/11/9

Y1 - 2007/11/9

N2 - In the centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The Ag - P bond distances are 2.4615 (7) and 2.5091 (7) Å, while the Ag - N and the Ag - S bond distances are 2.364 (2) and 2.3269 (18) Å, respectively. The crystal structure exhibits C - H⋯S hydrogen bonds.

AB - In the centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The Ag - P bond distances are 2.4615 (7) and 2.5091 (7) Å, while the Ag - N and the Ag - S bond distances are 2.364 (2) and 2.3269 (18) Å, respectively. The crystal structure exhibits C - H⋯S hydrogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=36849041210&partnerID=8YFLogxK

U2 - 10.1107/S1600536807058837

DO - 10.1107/S1600536807058837

M3 - Article

AN - SCOPUS:36849041210

SN - 1600-5368

VL - 63

SP - m3076-m3077

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Di -μ- thiocyanato-bis[bis(tri-p-tolyl-phosphine)silver(I)] acetonitrile disolvate

Abstract

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