Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate

Nozipho M. Khumalo; Reinout Meijboom; Alfred Muller; Bernard Omondi

doi:10.1107/S1600536810010032

Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate

Nozipho M. Khumalo, Reinout Meijboom, Alfred Muller, Bernard Omondi

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the binuclear centrosymmetric title compound, [Ag₂(NCS) ₂(C₂₁H₂₁P)₄]·0.35H ₂O, a pseudo-polymorph of [Ag₂(NCS)₂(C ₂₁H₂₁P)₄]·2CH₃CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C - H⋯π inter-actions.

Original language	English
Pages (from-to)	m451-m452
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	4
DOIs	https://doi.org/10.1107/S1600536810010032
Publication status	Published - 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate",

abstract = "In the binuclear centrosymmetric title compound, [Ag2(NCS) 2(C21H21P)4]·0.35H 2O, a pseudo-polymorph of [Ag2(NCS)2(C 21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C - H⋯π inter-actions.",

author = "Khumalo, \{Nozipho M.\} and Reinout Meijboom and Alfred Muller and Bernard Omondi",

year = "2010",

doi = "10.1107/S1600536810010032",

language = "English",

volume = "66",

pages = "m451--m452",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate

AU - Khumalo, Nozipho M.

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Omondi, Bernard

PY - 2010

Y1 - 2010

N2 - In the binuclear centrosymmetric title compound, [Ag2(NCS) 2(C21H21P)4]·0.35H 2O, a pseudo-polymorph of [Ag2(NCS)2(C 21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C - H⋯π inter-actions.

AB - In the binuclear centrosymmetric title compound, [Ag2(NCS) 2(C21H21P)4]·0.35H 2O, a pseudo-polymorph of [Ag2(NCS)2(C 21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C - H⋯π inter-actions.

UR - https://www.scopus.com/pages/publications/77951212827

U2 - 10.1107/S1600536810010032

DO - 10.1107/S1600536810010032

M3 - Article

AN - SCOPUS:77951212827

SN - 1600-5368

VL - 66

SP - m451-m452

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate

Abstract

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