Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

Reinout Meijboom; Alfred Muller

doi:10.1107/S1600536806043601

Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

University of The Free State

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The title compound, [Ag₂I₂(C₅H ₅N)₂(C₂₁H₂₁P)₂], has C_i molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The Ag⋯Ag separation in the binuclear species is 3.1130 (18) Å. The Ag-P distance is 2.4489 (12) Å, the Ag-N distance is 2.392 (3) Å, and the Ag-I distances are 2.8402 (14) and 2.8644 (8) Å.

Original language	English
Pages (from-to)	m3191-m3193
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	12
DOIs	https://doi.org/10.1107/S1600536806043601
Publication status	Published - Dec 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{629e0ca292e342af94eea26ac0f69016,

title = "Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]",

abstract = "The title compound, [Ag2I2(C5H 5N)2(C21H21P)2], has Ci molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The Ag⋯Ag separation in the binuclear species is 3.1130 (18) {\AA}. The Ag-P distance is 2.4489 (12) {\AA}, the Ag-N distance is 2.392 (3) {\AA}, and the Ag-I distances are 2.8402 (14) and 2.8644 (8) {\AA}.",

author = "Reinout Meijboom and Alfred Muller",

year = "2006",

month = dec,

doi = "10.1107/S1600536806043601",

language = "English",

volume = "62",

pages = "m3191--m3193",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

AU - Meijboom, Reinout

AU - Muller, Alfred

PY - 2006/12

Y1 - 2006/12

N2 - The title compound, [Ag2I2(C5H 5N)2(C21H21P)2], has Ci molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The Ag⋯Ag separation in the binuclear species is 3.1130 (18) Å. The Ag-P distance is 2.4489 (12) Å, the Ag-N distance is 2.392 (3) Å, and the Ag-I distances are 2.8402 (14) and 2.8644 (8) Å.

AB - The title compound, [Ag2I2(C5H 5N)2(C21H21P)2], has Ci molecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetrahedral coordination. The Ag⋯Ag separation in the binuclear species is 3.1130 (18) Å. The Ag-P distance is 2.4489 (12) Å, the Ag-N distance is 2.392 (3) Å, and the Ag-I distances are 2.8402 (14) and 2.8644 (8) Å.

UR - https://www.scopus.com/pages/publications/33845450658

U2 - 10.1107/S1600536806043601

DO - 10.1107/S1600536806043601

M3 - Article

AN - SCOPUS:33845450658

SN - 1600-5368

VL - 62

SP - m3191-m3193

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

Abstract

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