Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-P](pyridine-N) silver(I)}

Bernard Omondi; Reinout Meijboom

doi:10.1107/S160053680901099X

Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-P](pyridine-N) silver(I)}

Bernard Omondi, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [Ag₂I₂(C₅H ₅N)₂(C₁₈H₂₇P)₂], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag - P distance is 2.4436 (8) Å, Ag - N is 2.386 (3)Å and the Ag - I distances are 2.8186 (4) and 2.9449 (5) Å.

Original language	English
Pages (from-to)	m462-m463
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	4
DOIs	https://doi.org/10.1107/S160053680901099X
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{b044b7f67d2847c7988efd076880ab21,

title = "Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-P](pyridine-N) silver(I)}",

abstract = "The title compound, [Ag2I2(C5H 5N)2(C18H27P)2], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) {\AA}. The Ag - P distance is 2.4436 (8) {\AA}, Ag - N is 2.386 (3){\AA} and the Ag - I distances are 2.8186 (4) and 2.9449 (5) {\AA}.",

author = "Bernard Omondi and Reinout Meijboom",

year = "2009",

doi = "10.1107/S160053680901099X",

language = "English",

volume = "65",

pages = "m462--m463",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-P](pyridine-N) silver(I)}

AU - Omondi, Bernard

AU - Meijboom, Reinout

PY - 2009

Y1 - 2009

N2 - The title compound, [Ag2I2(C5H 5N)2(C18H27P)2], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag - P distance is 2.4436 (8) Å, Ag - N is 2.386 (3)Å and the Ag - I distances are 2.8186 (4) and 2.9449 (5) Å.

AB - The title compound, [Ag2I2(C5H 5N)2(C18H27P)2], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra-hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag - P distance is 2.4436 (8) Å, Ag - N is 2.386 (3)Å and the Ag - I distances are 2.8186 (4) and 2.9449 (5) Å.

UR - http://www.scopus.com/inward/record.url?scp=64149086578&partnerID=8YFLogxK

U2 - 10.1107/S160053680901099X

DO - 10.1107/S160053680901099X

M3 - Article

AN - SCOPUS:64149086578

SN - 1600-5368

VL - 65

SP - m462-m463

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Di-μ-iodido-bis-{[dicyclo-hexyl(phen-yl)phosphine-P](pyridine-N) silver(I)}

Abstract

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