Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl] naphthalen-1-yl-κ2 C 1,P}palladium(II)) dichloromethane disolvate

Wade L. Davis; Alfred Muller

doi:10.1107/S1600536812048222

Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl] naphthalen-1-yl-κ² C ¹,P}palladium(II)) dichloromethane disolvate

Wade L. Davis, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C-H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C-H⋯π and π-π [centroid-centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network.

Original language	English
Pages (from-to)	m1565-m1566
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812048222
Publication status	Published - Dec 2012

Keywords

R factor = 0.052
T = 100 K
data-to-parameter ratio = 19.5
mean ω(C-C) = 0.007 Å
single-crystal X-ray study
wR factor = 0.154

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536812048222

Cite this

@article{4846549e906749ccb71099339fa70681,

title = "Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl] naphthalen-1-yl-κ2 C 1,P}palladium(II)) dichloromethane disolvate",

abstract = "The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C-H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C-H⋯π and π-π [centroid-centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) {\AA}] interactions join these planes into a three-dimensional supermolecular network.",

keywords = "R factor = 0.052, T = 100 K, data-to-parameter ratio = 19.5, mean ω(C-C) = 0.007 {\AA}, single-crystal X-ray study, wR factor = 0.154",

author = "Davis, {Wade L.} and Alfred Muller",

year = "2012",

month = dec,

doi = "10.1107/S1600536812048222",

language = "English",

volume = "68",

pages = "m1565--m1566",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

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TY - JOUR

T1 - Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl] naphthalen-1-yl-κ2 C 1,P}palladium(II)) dichloromethane disolvate

AU - Davis, Wade L.

AU - Muller, Alfred

PY - 2012/12

Y1 - 2012/12

N2 - The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C-H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C-H⋯π and π-π [centroid-centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network.

AB - The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C-H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C-H⋯π and π-π [centroid-centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network.

KW - R factor = 0.052

KW - T = 100 K

KW - data-to-parameter ratio = 19.5

KW - mean ω(C-C) = 0.007 Å

KW - single-crystal X-ray study

KW - wR factor = 0.154

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U2 - 10.1107/S1600536812048222

DO - 10.1107/S1600536812048222

M3 - Article

AN - SCOPUS:84870893150

SN - 1600-5368

VL - 68

SP - m1565-m1566

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -