Determination of novel complexing agents in pulp and paper mill effluents and in lake water by liquid chromatography

Sirpa Metsärinne; Erja Ronkainen; Reijo Aksela; Tuula Tuhkanen; Mika Sillanpää

doi:10.1016/j.chroma.2005.07.087

Determination of novel complexing agents in pulp and paper mill effluents and in lake water by liquid chromatography

Sirpa Metsärinne
, Erja Ronkainen
, Reijo Aksela
, Tuula Tuhkanen
, Mika Sillanpää

University of Eastern Finland
Finnish Institute of Occupational Health
Kemira Oyj
Tampere University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A simple and sensitive high performance liquid chromatographic (HPLC) method with UV detection was developed for the determination of new diethanolamine derivative complexing agents. The quantitation of three complexing agents was accomplished as their Cu(II) complexes and their separation on a reversed phase C₁₈ column using 0.01 M tetrabutyl ammoniumhydroxide and methanol as isocratic mobile phase. The limit of detection (LOD) ranges from 0.1 to 2.0 mg/l and the method has a wide linear range, from LOD to 150 mg/l. The method was successfully applied for the analysis of lake water and wastewater effluent from pulp and paper mill spiked with studied complexing agents.

Original language	English
Pages (from-to)	56-59
Number of pages	4
Journal	Journal of Chromatography A
Volume	1094
Issue number	1-2
DOIs	https://doi.org/10.1016/j.chroma.2005.07.087
Publication status	Published - 11 Nov 2005
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 6 Clean Water and Sanitation
SDG 11 Sustainable Cities and Communities

Keywords

DTPA
Diethanolamine derivatives
EDTA
HPLC

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Organic Chemistry

Access to Document

10.1016/j.chroma.2005.07.087

Cite this

@article{dff40bb07824405ba9f1032b94a527c4,

title = "Determination of novel complexing agents in pulp and paper mill effluents and in lake water by liquid chromatography",

abstract = "A simple and sensitive high performance liquid chromatographic (HPLC) method with UV detection was developed for the determination of new diethanolamine derivative complexing agents. The quantitation of three complexing agents was accomplished as their Cu(II) complexes and their separation on a reversed phase C18 column using 0.01 M tetrabutyl ammoniumhydroxide and methanol as isocratic mobile phase. The limit of detection (LOD) ranges from 0.1 to 2.0 mg/l and the method has a wide linear range, from LOD to 150 mg/l. The method was successfully applied for the analysis of lake water and wastewater effluent from pulp and paper mill spiked with studied complexing agents.",

keywords = "DTPA, Diethanolamine derivatives, EDTA, HPLC",

author = "Sirpa Mets{\"a}rinne and Erja Ronkainen and Reijo Aksela and Tuula Tuhkanen and Mika Sillanp{\"a}{\"a}",

year = "2005",

month = nov,

day = "11",

doi = "10.1016/j.chroma.2005.07.087",

language = "English",

volume = "1094",

pages = "56--59",

journal = "Journal of Chromatography A",

issn = "0021-9673",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Determination of novel complexing agents in pulp and paper mill effluents and in lake water by liquid chromatography

AU - Metsärinne, Sirpa

AU - Ronkainen, Erja

AU - Aksela, Reijo

AU - Tuhkanen, Tuula

AU - Sillanpää, Mika

PY - 2005/11/11

Y1 - 2005/11/11

N2 - A simple and sensitive high performance liquid chromatographic (HPLC) method with UV detection was developed for the determination of new diethanolamine derivative complexing agents. The quantitation of three complexing agents was accomplished as their Cu(II) complexes and their separation on a reversed phase C18 column using 0.01 M tetrabutyl ammoniumhydroxide and methanol as isocratic mobile phase. The limit of detection (LOD) ranges from 0.1 to 2.0 mg/l and the method has a wide linear range, from LOD to 150 mg/l. The method was successfully applied for the analysis of lake water and wastewater effluent from pulp and paper mill spiked with studied complexing agents.

AB - A simple and sensitive high performance liquid chromatographic (HPLC) method with UV detection was developed for the determination of new diethanolamine derivative complexing agents. The quantitation of three complexing agents was accomplished as their Cu(II) complexes and their separation on a reversed phase C18 column using 0.01 M tetrabutyl ammoniumhydroxide and methanol as isocratic mobile phase. The limit of detection (LOD) ranges from 0.1 to 2.0 mg/l and the method has a wide linear range, from LOD to 150 mg/l. The method was successfully applied for the analysis of lake water and wastewater effluent from pulp and paper mill spiked with studied complexing agents.

KW - DTPA

KW - Diethanolamine derivatives

KW - EDTA

KW - HPLC

UR - https://www.scopus.com/pages/publications/27344433262

U2 - 10.1016/j.chroma.2005.07.087

DO - 10.1016/j.chroma.2005.07.087

M3 - Article

C2 - 16257289

AN - SCOPUS:27344433262

SN - 0021-9673

VL - 1094

SP - 56

EP - 59

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 1-2

ER -

Determination of novel complexing agents in pulp and paper mill effluents and in lake water by liquid chromatography

Abstract

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this