Abstract
Efficient palladium catalyst systems based on the combination of bench stable biaryl phosphacycles and Pd(OAc)2 are described for Suzuki-Miyaura cross-coupling reactions of aryl bromides and chlorides. Notably, the electronically and sterically diametric biaryl phosphacycles allowed facile coupling of sterically hindered and heterocyclic substrates.
Original language | English |
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Pages (from-to) | 587-592 |
Number of pages | 6 |
Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
Volume | 197 |
Issue number | 5-6 |
DOIs | |
Publication status | Published - 2022 |
Keywords
- Biaryl phosphacycles
- cross-coupling
- electronic
- steric
- Suzuki-Miyaura
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Inorganic Chemistry