Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate

Samson O. Owalude; Uche B. Eke; Ezekiel O. Odebunmi; Vladimir N. Nesterov; Reinout Meijboom; Neil J. Coville

doi:10.2116/xraystruct.28.29

Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate

Samson O. Owalude
, Uche B. Eke
, Ezekiel O. Odebunmi
, Vladimir N. Nesterov
, Reinout Meijboom
, Neil J. Coville

Chemical Sciences

University of Ilorin
University of North Texas
University of the Witwatersrand

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The salt [RuH(COD)(H₂NNH₂)₃][BPh₄] (2) (COD = cycloocta-1,5-diene and BPh₄ = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl₂}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P2₁/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012

Original language	English
Pages (from-to)	29-30
Number of pages	2
Journal	X-ray Structure Analysis Online
Volume	28
Issue number	4
DOIs	https://doi.org/10.2116/xraystruct.28.29
Publication status	Published - 2012

ASJC Scopus subject areas

Analytical Chemistry
Materials Chemistry

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10.2116/xraystruct.28.29

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@article{a5da788905154de884f7fbdd24cd8e8b,

title = "Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate",

abstract = "The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [\{Ru(COD)Cl2\}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8){\AA}, b = 32.881(3){\AA}, c = 18.6962(16){\AA}, β = 99.571(10)°, V = 5907.3(9){\AA}3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012",

author = "Owalude, \{Samson O.\} and Eke, \{Uche B.\} and Odebunmi, \{Ezekiel O.\} and Nesterov, \{Vladimir N.\} and Reinout Meijboom and Coville, \{Neil J.\}",

year = "2012",

doi = "10.2116/xraystruct.28.29",

language = "English",

volume = "28",

pages = "29--30",

journal = "X-ray Structure Analysis Online",

issn = "1883-3578",

publisher = "Japan Society for Analytical Chemistry",

number = "4",

}

TY - JOUR

T1 - Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate

AU - Owalude, Samson O.

AU - Eke, Uche B.

AU - Odebunmi, Ezekiel O.

AU - Nesterov, Vladimir N.

AU - Meijboom, Reinout

AU - Coville, Neil J.

PY - 2012

Y1 - 2012

N2 - The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl2}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012

AB - The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl2}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012

UR - https://www.scopus.com/pages/publications/84864142712

U2 - 10.2116/xraystruct.28.29

DO - 10.2116/xraystruct.28.29

M3 - Article

AN - SCOPUS:84864142712

SN - 1883-3578

VL - 28

SP - 29

EP - 30

JO - X-ray Structure Analysis Online

JF - X-ray Structure Analysis Online

IS - 4

ER -

Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate

Abstract

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