TY - JOUR
T1 - Crystal structure of (cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium(ii) tetraphenylborate
AU - Owalude, Samson O.
AU - Eke, Uche B.
AU - Odebunmi, Ezekiel O.
AU - Nesterov, Vladimir N.
AU - Meijboom, Reinout
AU - Coville, Neil J.
PY - 2012
Y1 - 2012
N2 - The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl2}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012
AB - The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl2}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, β = 99.571(10)°, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. 2012
UR - http://www.scopus.com/inward/record.url?scp=84864142712&partnerID=8YFLogxK
U2 - 10.2116/xraystruct.28.29
DO - 10.2116/xraystruct.28.29
M3 - Article
AN - SCOPUS:84864142712
SN - 1883-3578
VL - 28
SP - 29
EP - 30
JO - X-ray Structure Analysis Online
JF - X-ray Structure Analysis Online
IS - 4
ER -