Crystal structure of copper bis(tenuazonate) monohydrate

A. Dippenaar; C. W. Holzapfel; J. C.A. Boeyens

doi:10.1007/BF01371471

Crystal structure of copper bis(tenuazonate) monohydrate

A. Dippenaar, C. W. Holzapfel, J. C.A. Boeyens

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic, P2₁, with a = 13.77(1), b = 15.51(1), c = 11.14(1) Å, β = 109.5(2) °, and two formula units, C₂₀H₂₆CuN₂O₆·H₂O, per asymmetric unit. The structure was refined by full-matrix least squares to R = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.

Original language	English
Pages (from-to)	189-197
Number of pages	9
Journal	Journal of Crystal and Molecular Structure
Volume	7
Issue number	4
DOIs	https://doi.org/10.1007/BF01371471
Publication status	Published - Aug 1977

ASJC Scopus subject areas

Structural Biology
Condensed Matter Physics
Spectroscopy

Access to Document

10.1007/BF01371471

Cite this

@article{3f30f3c350a34d95a118db7dbd729e0a,

title = "Crystal structure of copper bis(tenuazonate) monohydrate",

abstract = "The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic, P21, with a = 13.77(1), b = 15.51(1), c = 11.14(1) {\AA}, β = 109.5(2) °, and two formula units, C20H26CuN2O6·H2O, per asymmetric unit. The structure was refined by full-matrix least squares to R = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.",

author = "A. Dippenaar and Holzapfel, {C. W.} and Boeyens, {J. C.A.}",

year = "1977",

month = aug,

doi = "10.1007/BF01371471",

language = "English",

volume = "7",

pages = "189--197",

journal = "Journal of Crystal and Molecular Structure",

issn = "0308-4086",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - Crystal structure of copper bis(tenuazonate) monohydrate

AU - Dippenaar, A.

AU - Holzapfel, C. W.

AU - Boeyens, J. C.A.

PY - 1977/8

Y1 - 1977/8

N2 - The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic, P21, with a = 13.77(1), b = 15.51(1), c = 11.14(1) Å, β = 109.5(2) °, and two formula units, C20H26CuN2O6·H2O, per asymmetric unit. The structure was refined by full-matrix least squares to R = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.

AB - The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic, P21, with a = 13.77(1), b = 15.51(1), c = 11.14(1) Å, β = 109.5(2) °, and two formula units, C20H26CuN2O6·H2O, per asymmetric unit. The structure was refined by full-matrix least squares to R = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.

UR - http://www.scopus.com/inward/record.url?scp=34250300218&partnerID=8YFLogxK

U2 - 10.1007/BF01371471

DO - 10.1007/BF01371471

M3 - Article

AN - SCOPUS:34250300218

SN - 0308-4086

VL - 7

SP - 189

EP - 197

JO - Journal of Crystal and Molecular Structure

JF - Journal of Crystal and Molecular Structure

IS - 4

ER -

Crystal structure of copper bis(tenuazonate) monohydrate

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this