Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems

Rafique Ul Islam; Michael J. Witcomb; Michael S. Scurrell; Elma Van Der Lingen; Willem Van Otterlo; Kaushik Mallick

doi:10.1039/c0cy00071j

Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems

Rafique Ul Islam, Michael J. Witcomb, Michael S. Scurrell, Elma Van Der Lingen, Willem Van Otterlo, Kaushik Mallick

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

A simple and efficient procedure for Suzuki coupling of aryl bromides with phenylboronic acid, catalyzed by an in situ-generated palladium(0)-polymer composite in the absence of any phosphine ligand, has been reported. The catalyst is remarkably active having a high TOF value for both aryl and heteroaryl systems, and is recyclable up to three runs with minimum loss of efficiency.

Original language	English
Pages (from-to)	308-315
Number of pages	8
Journal	Catalysis Science and Technology
Volume	1
Issue number	2
DOIs	https://doi.org/10.1039/c0cy00071j
Publication status	Published - May 2011
Externally published	Yes

ASJC Scopus subject areas

Catalysis

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10.1039/c0cy00071j

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title = "Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems",

abstract = "A simple and efficient procedure for Suzuki coupling of aryl bromides with phenylboronic acid, catalyzed by an in situ-generated palladium(0)-polymer composite in the absence of any phosphine ligand, has been reported. The catalyst is remarkably active having a high TOF value for both aryl and heteroaryl systems, and is recyclable up to three runs with minimum loss of efficiency.",

author = "Islam, {Rafique Ul} and Witcomb, {Michael J.} and Scurrell, {Michael S.} and {Van Der Lingen}, Elma and {Van Otterlo}, Willem and Kaushik Mallick",

year = "2011",

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doi = "10.1039/c0cy00071j",

language = "English",

volume = "1",

pages = "308--315",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

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Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems. / Islam, Rafique Ul; Witcomb, Michael J.; Scurrell, Michael S. et al.
In: Catalysis Science and Technology, Vol. 1, No. 2, 05.2011, p. 308-315.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems

AU - Islam, Rafique Ul

AU - Witcomb, Michael J.

AU - Scurrell, Michael S.

AU - Van Der Lingen, Elma

AU - Van Otterlo, Willem

AU - Mallick, Kaushik

PY - 2011/5

Y1 - 2011/5

N2 - A simple and efficient procedure for Suzuki coupling of aryl bromides with phenylboronic acid, catalyzed by an in situ-generated palladium(0)-polymer composite in the absence of any phosphine ligand, has been reported. The catalyst is remarkably active having a high TOF value for both aryl and heteroaryl systems, and is recyclable up to three runs with minimum loss of efficiency.

AB - A simple and efficient procedure for Suzuki coupling of aryl bromides with phenylboronic acid, catalyzed by an in situ-generated palladium(0)-polymer composite in the absence of any phosphine ligand, has been reported. The catalyst is remarkably active having a high TOF value for both aryl and heteroaryl systems, and is recyclable up to three runs with minimum loss of efficiency.

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DO - 10.1039/c0cy00071j

M3 - Article

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VL - 1

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JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

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Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems

Abstract

ASJC Scopus subject areas

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