CIS-diphenylbis(1,3,5-triaza-7-phosphaadamantane-κP)platinum(II)

Alfred Muller; Andreas Roodt

doi:10.1107/S0108270104009096

CIS-diphenylbis(1,3,5-triaza-7-phosphaadamantane-κP)platinum(II)

Alfred Muller, Andreas Roodt

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The structure of the title compound, [Pt(C₆H₅) ₂(C₆H₁₂N₃P)₂] or [Pt(Ph)₂(PTA)₂] (where Ph is phenyl and PTA is 1,3,5-triaza-7-phosphaadamantane), is discussed. Selected geometric parameters are: Pt-P = 2.2888 (16) and 2.2944 (17) Å, Pt-C = 2.052 (5) and 2.064 (6) Å, C-Pt-C = 84.6 (2)° and P-Pt-P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.

Original language	English
Pages (from-to)	m266-m268
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	6
DOIs	https://doi.org/10.1107/S0108270104009096
Publication status	Published - Jun 2004

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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@article{4c90c41daad94657bf2a0d0ea60eef3e,

title = "CIS-diphenylbis(1,3,5-triaza-7-phosphaadamantane-κP)platinum(II)",

abstract = "The structure of the title compound, [Pt(C6H5) 2(C6H12N3P)2] or [Pt(Ph)2(PTA)2] (where Ph is phenyl and PTA is 1,3,5-triaza-7-phosphaadamantane), is discussed. Selected geometric parameters are: Pt-P = 2.2888 (16) and 2.2944 (17) {\AA}, Pt-C = 2.052 (5) and 2.064 (6) {\AA}, C-Pt-C = 84.6 (2)° and P-Pt-P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.",

author = "Alfred Muller and Andreas Roodt",

year = "2004",

month = jun,

doi = "10.1107/S0108270104009096",

language = "English",

volume = "60",

pages = "m266--m268",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - CIS-diphenylbis(1,3,5-triaza-7-phosphaadamantane-κP)platinum(II)

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2004/6

Y1 - 2004/6

N2 - The structure of the title compound, [Pt(C6H5) 2(C6H12N3P)2] or [Pt(Ph)2(PTA)2] (where Ph is phenyl and PTA is 1,3,5-triaza-7-phosphaadamantane), is discussed. Selected geometric parameters are: Pt-P = 2.2888 (16) and 2.2944 (17) Å, Pt-C = 2.052 (5) and 2.064 (6) Å, C-Pt-C = 84.6 (2)° and P-Pt-P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.

AB - The structure of the title compound, [Pt(C6H5) 2(C6H12N3P)2] or [Pt(Ph)2(PTA)2] (where Ph is phenyl and PTA is 1,3,5-triaza-7-phosphaadamantane), is discussed. Selected geometric parameters are: Pt-P = 2.2888 (16) and 2.2944 (17) Å, Pt-C = 2.052 (5) and 2.064 (6) Å, C-Pt-C = 84.6 (2)° and P-Pt-P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.

UR - http://www.scopus.com/inward/record.url?scp=3142611590&partnerID=8YFLogxK

U2 - 10.1107/S0108270104009096

DO - 10.1107/S0108270104009096

M3 - Article

AN - SCOPUS:3142611590

SN - 0108-2701

VL - 60

SP - m266-m268

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

CIS-diphenylbis(1,3,5-triaza-7-phosphaadamantane-κP)platinum(II)

Abstract

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