cis-dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate

Reinout Meijboom; Alfred Muller

doi:10.1107/S1600536806036634

cis-dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate

Reinout Meijboom, Alfred Muller

University of The Free State

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, cis-[PdCl₂{P(C₄H ₃O)₃}₂]·0.5CH₂Cl ₂, where P(C₄H₃O)₃ is tri-2-furylphosphine, the Pd^II centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) Å and Pd-Cl bond lengths are 2.3393(9) and 2.3501 (10) Å. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.

Original language	English
Pages (from-to)	m2642-m2644
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	10
DOIs	https://doi.org/10.1107/S1600536806036634
Publication status	Published - Oct 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "cis-dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate",

abstract = "In the title compound, cis-[PdCl2{P(C4H 3O)3}2]·0.5CH2Cl 2, where P(C4H3O)3 is tri-2-furylphosphine, the PdII centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) {\AA} and Pd-Cl bond lengths are 2.3393(9) and 2.3501 (10) {\AA}. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.",

author = "Reinout Meijboom and Alfred Muller",

year = "2006",

month = oct,

doi = "10.1107/S1600536806036634",

language = "English",

volume = "62",

pages = "m2642--m2644",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

}

TY - JOUR

T1 - cis-dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate

AU - Meijboom, Reinout

AU - Muller, Alfred

PY - 2006/10

Y1 - 2006/10

N2 - In the title compound, cis-[PdCl2{P(C4H 3O)3}2]·0.5CH2Cl 2, where P(C4H3O)3 is tri-2-furylphosphine, the PdII centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) Å and Pd-Cl bond lengths are 2.3393(9) and 2.3501 (10) Å. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.

AB - In the title compound, cis-[PdCl2{P(C4H 3O)3}2]·0.5CH2Cl 2, where P(C4H3O)3 is tri-2-furylphosphine, the PdII centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) Å and Pd-Cl bond lengths are 2.3393(9) and 2.3501 (10) Å. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.

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U2 - 10.1107/S1600536806036634

DO - 10.1107/S1600536806036634

M3 - Article

AN - SCOPUS:33749986499

SN - 1600-5368

VL - 62

SP - m2642-m2644

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

cis-dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate

Abstract

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