Cis-Dichloridobis{[4-(dimethylamino)-phenyl]diphenyl-phosphane-kP} platinum(II) ethyl acetate monosolvate

Alfred Muller; Reinout Meijboom

doi:10.1107/S1600536811035628

Cis-Dichloridobis{[4-(dimethylamino)-phenyl]diphenyl-phosphane-kP} platinum(II) ethyl acetate monosolvate

Alfred Muller, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [PtCl ₂(C ₂₀H ₂₀P) ₂]·C ₄H ₈O ₂, crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) Å, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) Å. Some weak C-H⋯Cl and C-H⋯O interactions involving the solvate molecule were observed.

Original language	English
Pages (from-to)	m1353
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	10
DOIs	https://doi.org/10.1107/S1600536811035628
Publication status	Published - Oct 2011

Keywords

R factor = 0.058
T = 100 K
data-to-parameter ratio = 20.8
mean σ(C-C) = 0.012 Å
single-crystal X-ray study
wR factor = 0.144

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{0728f21428e940528f63fbe7b558293d,

title = "Cis-Dichloridobis{[4-(dimethylamino)-phenyl]diphenyl-phosphane-kP} platinum(II) ethyl acetate monosolvate",

abstract = "The title compound, [PtCl 2(C 20H 20P) 2]·C 4H 8O 2, crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) {\AA}, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) {\AA}. Some weak C-H⋯Cl and C-H⋯O interactions involving the solvate molecule were observed.",

keywords = "R factor = 0.058, T = 100 K, data-to-parameter ratio = 20.8, mean σ(C-C) = 0.012 {\AA}, single-crystal X-ray study, wR factor = 0.144",

author = "Alfred Muller and Reinout Meijboom",

year = "2011",

month = oct,

doi = "10.1107/S1600536811035628",

language = "English",

volume = "67",

pages = "m1353",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

}

TY - JOUR

T1 - Cis-Dichloridobis{[4-(dimethylamino)-phenyl]diphenyl-phosphane-kP} platinum(II) ethyl acetate monosolvate

AU - Muller, Alfred

AU - Meijboom, Reinout

PY - 2011/10

Y1 - 2011/10

N2 - The title compound, [PtCl 2(C 20H 20P) 2]·C 4H 8O 2, crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) Å, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) Å. Some weak C-H⋯Cl and C-H⋯O interactions involving the solvate molecule were observed.

AB - The title compound, [PtCl 2(C 20H 20P) 2]·C 4H 8O 2, crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) Å, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) Å. Some weak C-H⋯Cl and C-H⋯O interactions involving the solvate molecule were observed.

KW - R factor = 0.058

KW - T = 100 K

KW - data-to-parameter ratio = 20.8

KW - mean σ(C-C) = 0.012 Å

KW - single-crystal X-ray study

KW - wR factor = 0.144

UR - http://www.scopus.com/inward/record.url?scp=80055011615&partnerID=8YFLogxK

U2 - 10.1107/S1600536811035628

DO - 10.1107/S1600536811035628

M3 - Article

AN - SCOPUS:80055011615

SN - 1600-5368

VL - 67

SP - m1353

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Cis-Dichloridobis{[4-(dimethylamino)-phenyl]diphenyl-phosphane-kP} platinum(II) ethyl acetate monosolvate

Abstract

Keywords

ASJC Scopus subject areas

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