Cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-kN 2)ethanamine- kN]palladium(II) dichloro-methane monosolvate

Collins Obuah; James Darkwa; Alfred Muller

doi:10.1107/S1600536812032308

Cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-kN ²)ethanamine- kN]palladium(II) dichloro-methane monosolvate

Collins Obuah, James Darkwa, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [PdC_l2(C₇H₁₃N ₃)]·CH₂C_l2, the 2-(3,5-dimethyl-1H- pyrazol-1-yl)ethanamine ligand chelates the Pd^II atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.

Original language	English
Pages (from-to)	m1103
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	8
DOIs	https://doi.org/10.1107/S1600536812032308
Publication status	Published - Aug 2012

Keywords

R factor = 0.032
T = 100 K
data-to-parameter ratio = 23.1
mean σ(C-C) = 0.005 Å
single-crystal X-ray study
wR factor = 0.085

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536812032308

Cite this

@article{d2034d98616c4c3686069305f131db4c,

title = "Cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-kN 2)ethanamine- kN]palladium(II) dichloro-methane monosolvate",

abstract = "In the title compound, [PdCl2(C7H13N 3)]·CH2Cl2, the 2-(3,5-dimethyl-1H- pyrazol-1-yl)ethanamine ligand chelates the PdII atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.",

keywords = "R factor = 0.032, T = 100 K, data-to-parameter ratio = 23.1, mean σ(C-C) = 0.005 {\AA}, single-crystal X-ray study, wR factor = 0.085",

author = "Collins Obuah and James Darkwa and Alfred Muller",

year = "2012",

month = aug,

doi = "10.1107/S1600536812032308",

language = "English",

volume = "68",

pages = "m1103",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - Cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-kN 2)ethanamine- kN]palladium(II) dichloro-methane monosolvate

AU - Obuah, Collins

AU - Darkwa, James

AU - Muller, Alfred

PY - 2012/8

Y1 - 2012/8

N2 - In the title compound, [PdCl2(C7H13N 3)]·CH2Cl2, the 2-(3,5-dimethyl-1H- pyrazol-1-yl)ethanamine ligand chelates the PdII atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.

AB - In the title compound, [PdCl2(C7H13N 3)]·CH2Cl2, the 2-(3,5-dimethyl-1H- pyrazol-1-yl)ethanamine ligand chelates the PdII atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure.

KW - R factor = 0.032

KW - T = 100 K

KW - data-to-parameter ratio = 23.1

KW - mean σ(C-C) = 0.005 Å

KW - single-crystal X-ray study

KW - wR factor = 0.085

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U2 - 10.1107/S1600536812032308

DO - 10.1107/S1600536812032308

M3 - Article

AN - SCOPUS:84864674818

SN - 1600-5368

VL - 68

SP - m1103

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -