Cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate

Wade L. Davis; Reinout Meijboom

doi:10.1107/S1600536811049269

Cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate

Wade L. Davis, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, [PtCl₂(C ₁₉H₁₇P)₂]₂·3CH ₂Cl₂, contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The Pt^II complexes reveal a slightly distorted square-planar geometry with average Pt - P and Pt - Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P - Pt- P and Cl - Pt - Cl angles of 99.17 (8) and 87.1 (7)°, respectively.

Original language	English
Pages (from-to)	m1800
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811049269
Publication status	Published - Dec 2011

Keywords

R factor = 0.020
T = 100 K
data-toparameter ratio = 21.6
disorder in solvent or counterion
mean σ(C-C) = 0.003 Å
single-crystal X-ray study
wR factor = 0.049

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536811049269

Cite this

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title = "Cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate",

abstract = "The asymmetric unit of the title compound, [PtCl2(C 19H17P)2]2·3CH 2Cl2, contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The PtII complexes reveal a slightly distorted square-planar geometry with average Pt - P and Pt - Cl bond lengthss of 2.252 (8) and 2.363 (8) {\AA}, respectively, and average P - Pt- P and Cl - Pt - Cl angles of 99.17 (8) and 87.1 (7)°, respectively.",

keywords = "R factor = 0.020, T = 100 K, data-toparameter ratio = 21.6, disorder in solvent or counterion, mean σ(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.049",

author = "Davis, {Wade L.} and Reinout Meijboom",

year = "2011",

month = dec,

doi = "10.1107/S1600536811049269",

language = "English",

volume = "67",

pages = "m1800",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate

AU - Davis, Wade L.

AU - Meijboom, Reinout

PY - 2011/12

Y1 - 2011/12

N2 - The asymmetric unit of the title compound, [PtCl2(C 19H17P)2]2·3CH 2Cl2, contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The PtII complexes reveal a slightly distorted square-planar geometry with average Pt - P and Pt - Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P - Pt- P and Cl - Pt - Cl angles of 99.17 (8) and 87.1 (7)°, respectively.

AB - The asymmetric unit of the title compound, [PtCl2(C 19H17P)2]2·3CH 2Cl2, contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The PtII complexes reveal a slightly distorted square-planar geometry with average Pt - P and Pt - Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P - Pt- P and Cl - Pt - Cl angles of 99.17 (8) and 87.1 (7)°, respectively.

KW - R factor = 0.020

KW - T = 100 K

KW - data-toparameter ratio = 21.6

KW - disorder in solvent or counterion

KW - mean σ(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.049

UR - http://www.scopus.com/inward/record.url?scp=83155178526&partnerID=8YFLogxK

U2 - 10.1107/S1600536811049269

DO - 10.1107/S1600536811049269

M3 - Article

AN - SCOPUS:83155178526

SN - 1600-5368

VL - 67

SP - m1800

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate

Abstract

Keywords

ASJC Scopus subject areas

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