Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ2 N,P}methylpalladium(II) dichloromethane hemisolvate

Martin O. Onani; William M. Motswainyana; Emmanuel I. Iwuoha; James Darkwa; Roger A. Lalancette

doi:10.1107/S1600536810017824

Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ² N,P}methylpalladium(II) dichloromethane hemisolvate

Martin O. Onani
, William M. Motswainyana
, Emmanuel I. Iwuoha
, James Darkwa
, Roger A. Lalancette

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In the title compound, [Pd(CH₃)Cl(C₂₅H ₂₂NPS)]·0.5C₂H₂Cl₂, the Pd^II atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.

Original language	English
Pages (from-to)	m688
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	6
DOIs	https://doi.org/10.1107/S1600536810017824
Publication status	Published - 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{449179a148ef41a9b2d16a4074994a09,

title = "Chlorido\{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ2 N,P\}methylpalladium(II) dichloromethane hemisolvate",

abstract = "In the title compound, [Pd(CH3)Cl(C25H 22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.",

author = "Onani, \{Martin O.\} and Motswainyana, \{William M.\} and Iwuoha, \{Emmanuel I.\} and James Darkwa and Lalancette, \{Roger A.\}",

year = "2010",

doi = "10.1107/S1600536810017824",

language = "English",

volume = "66",

pages = "m688",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ2 N,P}methylpalladium(II) dichloromethane hemisolvate

AU - Onani, Martin O.

AU - Motswainyana, William M.

AU - Iwuoha, Emmanuel I.

AU - Darkwa, James

AU - Lalancette, Roger A.

PY - 2010

Y1 - 2010

N2 - In the title compound, [Pd(CH3)Cl(C25H 22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.

AB - In the title compound, [Pd(CH3)Cl(C25H 22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.

UR - https://www.scopus.com/pages/publications/77953193607

U2 - 10.1107/S1600536810017824

DO - 10.1107/S1600536810017824

M3 - Article

AN - SCOPUS:77953193607

SN - 1600-5368

VL - 66

SP - m688

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ² N,P}methylpalladium(II) dichloromethane hemisolvate

Abstract

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