TY - JOUR
T1 - Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl) ethanamine-κ2 N,P}methylpalladium(II) dichloromethane hemisolvate
AU - Onani, Martin O.
AU - Motswainyana, William M.
AU - Iwuoha, Emmanuel I.
AU - Darkwa, James
AU - Lalancette, Roger A.
PY - 2010
Y1 - 2010
N2 - In the title compound, [Pd(CH3)Cl(C25H 22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.
AB - In the title compound, [Pd(CH3)Cl(C25H 22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.
UR - http://www.scopus.com/inward/record.url?scp=77953193607&partnerID=8YFLogxK
U2 - 10.1107/S1600536810017824
DO - 10.1107/S1600536810017824
M3 - Article
AN - SCOPUS:77953193607
SN - 1600-5368
VL - 66
SP - m688
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 6
ER -