Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2 N1,S)diphenyltin(IV)

Ramaiyer Venkatraman; Lungile Sitole; Frank R. Fronczek

doi:10.1107/S1600536809047400

Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ² N¹,S)diphenyltin(IV)

Ramaiyer Venkatraman
, Lungile Sitole
, Frank R. Fronczek

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The Sn atom in the title compound, [Sn(C₆H₅) ₂(C₈H₁₄N₃S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4- ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N - H⋯Cl hydrogen bonds form chains along [101].

Original language	English
Pages (from-to)	m1653-m1654
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	12
DOIs	https://doi.org/10.1107/S1600536809047400
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2 N1,S)diphenyltin(IV)",

abstract = "The Sn atom in the title compound, [Sn(C6H5) 2(C8H14N3S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4- ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N - H⋯Cl hydrogen bonds form chains along [101].",

author = "Ramaiyer Venkatraman and Lungile Sitole and Fronczek, \{Frank R.\}",

year = "2009",

doi = "10.1107/S1600536809047400",

language = "English",

volume = "65",

pages = "m1653--m1654",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

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T1 - Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ2 N1,S)diphenyltin(IV)

AU - Venkatraman, Ramaiyer

AU - Sitole, Lungile

AU - Fronczek, Frank R.

PY - 2009

Y1 - 2009

N2 - The Sn atom in the title compound, [Sn(C6H5) 2(C8H14N3S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4- ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N - H⋯Cl hydrogen bonds form chains along [101].

AB - The Sn atom in the title compound, [Sn(C6H5) 2(C8H14N3S)Cl], is penta-coordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclo-pentyl-idene-4- ethyl-thio-semicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclo-pentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, inter-molecular N - H⋯Cl hydrogen bonds form chains along [101].

UR - https://www.scopus.com/pages/publications/72049110791

U2 - 10.1107/S1600536809047400

DO - 10.1107/S1600536809047400

M3 - Article

AN - SCOPUS:72049110791

SN - 1600-5368

VL - 65

SP - m1653-m1654

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-κ² N¹,S)diphenyltin(IV)

Abstract

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