Chemostratigraphic constraints on early Ediacaran carbonate ramp dynamics, Río de la Plata craton, Uruguay

Natalie R. Aubet, Ernesto Pecoits, Andrey Bekker, Murray K. Gingras, Horst Zwingmann, Gerardo Veroslavsky, Héctor de Santa Ana, Kurt O. Konhauser

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

C- and Sr-isotope data for marine carbonates can provide a detailed record of isotopic variations in seawater through time and have proven to be a valuable tool for interpreting biogeochemical events and correlating Neoproterozoic sedimentary successions worldwide. Negative carbon isotope excursion to values as low as -4.5‰ in the Ediacaran Polanco Limestones Formation, Uruguay has been interpreted as recording the aftermath of a post-Gaskiers glacial event occurred elsewhere on southwest Gondwana. The record of both deep- and shallow-water settings in the Polanco Limestone Formation provides an opportunity to examine δ13C variability across the platform and to evaluate whether the carbon isotope values reflect local or global processes. Herein we provide high-resolution δ13C-chemostratigraphy and Sr-isotope data from stratigraphic sections comprising proximal and distal settings on the carbonate platform. Carbon isotopic values are negative in deep-water facies but progressively rise towards positive values in shallow-water settings. This previously unrecognized trend suggests that deposition of Polanco carbonates occurred in a stratified marine basin where degradation of organic matter below the redox boundary led to lower δ13C values at greater depths. The negative δ13C excursion is restricted to specific horizons in shallow-water facies and is interpreted as being originated due to higher levels of reworking under storm-dominated conditions, which produced a strong local oxidation of organic matter and ultimately, the negative carbon isotope signatures. 87Sr/86Sr and δ13C chemostratigraphy coupled with new radiometric data allow us to revise the previously proposed age for the unit. This new data support an age between 590 and 560Ma for the deposition of the Polanco Limestones Formation.

Original languageEnglish
Pages (from-to)1073-1090
Number of pages18
JournalGondwana Research
Volume22
Issue number3-4
DOIs
Publication statusPublished - Nov 2012
Externally publishedYes

Keywords

  • Basin stratification
  • Chemostratigraphy
  • Ediacaran
  • KAr illite geochronology
  • Uruguay

ASJC Scopus subject areas

  • Geology

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