Cationic complexes of monovalent nickel as catalysts for styrene polymerization

V. V. Saraev; P. B. Kraikivskii; V. V. Annenkov; A. I. Vil'ms; D. A. Matveev; E. N. Danilovtseva; T. G. Ermakova; N. P. Kuznetsova; K. Lammertsma

doi:10.1007/s10975-005-0126-4

Cationic complexes of monovalent nickel as catalysts for styrene polymerization

V. V. Saraev
, P. B. Kraikivskii
, V. V. Annenkov
, A. I. Vil'ms
, D. A. Matveev
, E. N. Danilovtseva
, T. G. Ermakova
, N. P. Kuznetsova
, K. Lammertsma

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The interaction of the [Ni(PPh₃)₃]BF₄ complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and ¹³C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh₃)₃]BF₄ cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

Original language	English
Pages (from-to)	712-718
Number of pages	7
Journal	Kinetics and Catalysis
Volume	46
Issue number	5
DOIs	https://doi.org/10.1007/s10975-005-0126-4
Publication status	Published - Sept 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Modeling and Simulation
Computer Science Applications

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10.1007/s10975-005-0126-4

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@article{ca6372eee68e423086362f600da6b19c,

title = "Cationic complexes of monovalent nickel as catalysts for styrene polymerization",

abstract = "The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.",

author = "Saraev, \{V. V.\} and Kraikivskii, \{P. B.\} and Annenkov, \{V. V.\} and Vil'ms, \{A. I.\} and Matveev, \{D. A.\} and Danilovtseva, \{E. N.\} and Ermakova, \{T. G.\} and Kuznetsova, \{N. P.\} and K. Lammertsma",

year = "2005",

month = sep,

doi = "10.1007/s10975-005-0126-4",

language = "English",

volume = "46",

pages = "712--718",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "Maik Nauka Publishing / Springer SBM",

number = "5",

}

TY - JOUR

T1 - Cationic complexes of monovalent nickel as catalysts for styrene polymerization

AU - Saraev, V. V.

AU - Kraikivskii, P. B.

AU - Annenkov, V. V.

AU - Vil'ms, A. I.

AU - Matveev, D. A.

AU - Danilovtseva, E. N.

AU - Ermakova, T. G.

AU - Kuznetsova, N. P.

AU - Lammertsma, K.

PY - 2005/9

Y1 - 2005/9

N2 - The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

AB - The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

UR - https://www.scopus.com/pages/publications/27744444283

U2 - 10.1007/s10975-005-0126-4

DO - 10.1007/s10975-005-0126-4

M3 - Article

AN - SCOPUS:27744444283

SN - 0023-1584

VL - 46

SP - 712

EP - 718

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 5

ER -

Cationic complexes of monovalent nickel as catalysts for styrene polymerization

Abstract

ASJC Scopus subject areas

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