Cationic complexes of monovalent nickel as catalysts for styrene polymerization

V. V. Saraev; P. B. Kraikivskii; V. V. Annenkov; A. I. Vil'ms; D. A. Matveev; E. N. Danilovtseva; T. G. Ermakova; N. P. Kuznetsova; K. Lammertsma

doi:10.1007/s10975-005-0126-4

Cationic complexes of monovalent nickel as catalysts for styrene polymerization

V. V. Saraev, P. B. Kraikivskii, V. V. Annenkov, A. I. Vil'ms, D. A. Matveev, E. N. Danilovtseva, T. G. Ermakova, N. P. Kuznetsova, K. Lammertsma

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The interaction of the [Ni(PPh₃)₃]BF₄ complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and ¹³C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh₃)₃]BF₄ cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

Original language	English
Pages (from-to)	712-718
Number of pages	7
Journal	Kinetics and Catalysis
Volume	46
Issue number	5
DOIs	https://doi.org/10.1007/s10975-005-0126-4
Publication status	Published - Sept 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Modeling and Simulation
Computer Science Applications

Access to Document

10.1007/s10975-005-0126-4

Cite this

@article{ca6372eee68e423086362f600da6b19c,

title = "Cationic complexes of monovalent nickel as catalysts for styrene polymerization",

abstract = "The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.",

author = "Saraev, {V. V.} and Kraikivskii, {P. B.} and Annenkov, {V. V.} and Vil'ms, {A. I.} and Matveev, {D. A.} and Danilovtseva, {E. N.} and Ermakova, {T. G.} and Kuznetsova, {N. P.} and K. Lammertsma",

year = "2005",

month = sep,

doi = "10.1007/s10975-005-0126-4",

language = "English",

volume = "46",

pages = "712--718",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "Pleiades Publishing",

number = "5",

}

TY - JOUR

T1 - Cationic complexes of monovalent nickel as catalysts for styrene polymerization

AU - Saraev, V. V.

AU - Kraikivskii, P. B.

AU - Annenkov, V. V.

AU - Vil'ms, A. I.

AU - Matveev, D. A.

AU - Danilovtseva, E. N.

AU - Ermakova, T. G.

AU - Kuznetsova, N. P.

AU - Lammertsma, K.

PY - 2005/9

Y1 - 2005/9

N2 - The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

AB - The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

UR - http://www.scopus.com/inward/record.url?scp=27744444283&partnerID=8YFLogxK

U2 - 10.1007/s10975-005-0126-4

DO - 10.1007/s10975-005-0126-4

M3 - Article

AN - SCOPUS:27744444283

SN - 0023-1584

VL - 46

SP - 712

EP - 718

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 5

ER -

Cationic complexes of monovalent nickel as catalysts for styrene polymerization

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this