catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ2O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ4O,O′:O′,O′′]

Kariska Potgieter; Frederick P. Malan; Reinout Meijboom; E. R.T. Tiekink

doi:10.1107/S2414314622007726

catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ²O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ⁴O,O′:O′,O′′]

Kariska Potgieter, Frederick P. Malan, Reinout Meijboom, E. R.T. Tiekink

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The structure of the title complex, [Ag2(NO3)2(C19H17P)2] n , reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape.

Original language	English
Article number	x220772
Journal	IUCrData
Volume	7
Issue number	Pt 8
DOIs	https://doi.org/10.1107/S2414314622007726
Publication status	Published - 1 Aug 2022

Keywords

benzyldiphenyl phosphine
crystal structure
nitrate
silver(I) complex

ASJC Scopus subject areas

Analytical Chemistry
Inorganic Chemistry
Organic Chemistry

Access to Document

10.1107/S2414314622007726

Cite this

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title = "catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ2O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ4O,O′:O′,O′′]",

abstract = "The structure of the title complex, [Ag2(NO3)2(C19H17P)2] n , reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape.",

keywords = "benzyldiphenyl phosphine, crystal structure, nitrate, silver(I) complex",

author = "Kariska Potgieter and Malan, {Frederick P.} and Reinout Meijboom and Tiekink, {E. R.T.}",

note = "Publisher Copyright: {\textcopyright} 2022 Potgieter et al.",

year = "2022",

month = aug,

day = "1",

doi = "10.1107/S2414314622007726",

language = "English",

volume = "7",

journal = "IUCrData",

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publisher = "International Union of Crystallography",

number = "Pt 8",

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TY - JOUR

T1 - catena-Poly[[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ2O:O′-[(benzyldiphenylphosphine-κP)silver(I)]-μ-nitrato-κ4O,O′:O′,O′′]

AU - Potgieter, Kariska

AU - Malan, Frederick P.

AU - Meijboom, Reinout

AU - Tiekink, E. R.T.

PY - 2022/8/1

Y1 - 2022/8/1

N2 - The structure of the title complex, [Ag2(NO3)2(C19H17P)2] n , reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape.

AB - The structure of the title complex, [Ag2(NO3)2(C19H17P)2] n , reveals a chain emanating from the coordination of one phosphine ligand to each silver(I) cation, as well as the bis-monodentate coordination of a bridging nitrato ligand (per Ag atom) and the bis-bidentate coordination of another bridging nitrato ligand (per Ag atom). The distorted four-coordinate Ag atoms are characterized by bonding angles that notably deviate from the ideal tetrahedral shape.

KW - benzyldiphenyl phosphine

KW - crystal structure

KW - nitrate

KW - silver(I) complex

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DO - 10.1107/S2414314622007726

M3 - Article

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