Catalysis of olefin oligomerization by Ni(I) complexes

Vitaliy V. Saraev; Petr B. Kraikivskii; Vadim V. Annenkov; Stanislav N. Zelinskiy; Dmitriy A. Matveev; Aleksey I. Vilms; Elena N. Danilovtseva; Koop Lammertsma

Catalysis of olefin oligomerization by Ni(I) complexes

Vitaliy V. Saraev, Petr B. Kraikivskii, Vadim V. Annenkov, Stanislav N. Zelinskiy, Dmitriy A. Matveev, Aleksey I. Vilms, Elena N. Danilovtseva, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Activity of nickel-complex catalysts is traditionally attributed with hydride Ni(II) complexes generated by oxidation of Ni(0) particles with Brønsted acids. In this work catalytic activity of Ni(I) complexes obtained in the system Ni(PPh₃)₄/BF₃· OEt₂ have been studied. On the basis of EPR and ¹H NMR data, the formation of dimeric catalytic complexes with ethylene and styrene has been found. Ethylene transformation on Ni(I) catalyst results in 1-butene, 2-butene and trimers mixture. In the case of styrene, the polymers with molecular mass 2500 were obtained. These polymers contain terminal double bonds which can be used in design of new graft copolymers.

Original language	English
Pages (from-to)	44-52
Number of pages	9
Journal	Arkivoc
Volume	2005
Issue number	15
Publication status	Published - 31 Aug 2005
Externally published	Yes

Keywords

Catalysis
Complex
Ethylene
Nickel
Oligomerization
Styrene

ASJC Scopus subject areas

Organic Chemistry

Cite this

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title = "Catalysis of olefin oligomerization by Ni(I) complexes",

abstract = "Activity of nickel-complex catalysts is traditionally attributed with hydride Ni(II) complexes generated by oxidation of Ni(0) particles with Br{\o}nsted acids. In this work catalytic activity of Ni(I) complexes obtained in the system Ni(PPh3)4/BF3· OEt2 have been studied. On the basis of EPR and 1H NMR data, the formation of dimeric catalytic complexes with ethylene and styrene has been found. Ethylene transformation on Ni(I) catalyst results in 1-butene, 2-butene and trimers mixture. In the case of styrene, the polymers with molecular mass 2500 were obtained. These polymers contain terminal double bonds which can be used in design of new graft copolymers.",

keywords = "Catalysis, Complex, Ethylene, Nickel, Oligomerization, Styrene",

author = "Saraev, {Vitaliy V.} and Kraikivskii, {Petr B.} and Annenkov, {Vadim V.} and Zelinskiy, {Stanislav N.} and Matveev, {Dmitriy A.} and Vilms, {Aleksey I.} and Danilovtseva, {Elena N.} and Koop Lammertsma",

year = "2005",

month = aug,

day = "31",

language = "English",

volume = "2005",

pages = "44--52",

journal = "Arkivoc",

issn = "1424-6376",

publisher = "Arkat USA",

number = "15",

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TY - JOUR

T1 - Catalysis of olefin oligomerization by Ni(I) complexes

AU - Saraev, Vitaliy V.

AU - Kraikivskii, Petr B.

AU - Annenkov, Vadim V.

AU - Zelinskiy, Stanislav N.

AU - Matveev, Dmitriy A.

AU - Vilms, Aleksey I.

AU - Danilovtseva, Elena N.

AU - Lammertsma, Koop

PY - 2005/8/31

Y1 - 2005/8/31

N2 - Activity of nickel-complex catalysts is traditionally attributed with hydride Ni(II) complexes generated by oxidation of Ni(0) particles with Brønsted acids. In this work catalytic activity of Ni(I) complexes obtained in the system Ni(PPh3)4/BF3· OEt2 have been studied. On the basis of EPR and 1H NMR data, the formation of dimeric catalytic complexes with ethylene and styrene has been found. Ethylene transformation on Ni(I) catalyst results in 1-butene, 2-butene and trimers mixture. In the case of styrene, the polymers with molecular mass 2500 were obtained. These polymers contain terminal double bonds which can be used in design of new graft copolymers.

AB - Activity of nickel-complex catalysts is traditionally attributed with hydride Ni(II) complexes generated by oxidation of Ni(0) particles with Brønsted acids. In this work catalytic activity of Ni(I) complexes obtained in the system Ni(PPh3)4/BF3· OEt2 have been studied. On the basis of EPR and 1H NMR data, the formation of dimeric catalytic complexes with ethylene and styrene has been found. Ethylene transformation on Ni(I) catalyst results in 1-butene, 2-butene and trimers mixture. In the case of styrene, the polymers with molecular mass 2500 were obtained. These polymers contain terminal double bonds which can be used in design of new graft copolymers.

KW - Catalysis

KW - Complex

KW - Ethylene

KW - Nickel

KW - Oligomerization

KW - Styrene

UR - http://www.scopus.com/inward/record.url?scp=24044537293&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:24044537293

SN - 1424-6376

VL - 2005

SP - 44

EP - 52

JO - Arkivoc

JF - Arkivoc

IS - 15

ER -

Catalysis of olefin oligomerization by Ni(I) complexes

Abstract

Keywords

ASJC Scopus subject areas

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