Carbonyl(cyclohexyldiphenylphosphine)(8-hydroxyquinolinato)rhodium(I)

J. Marthinus Janse Van Rensburg; Andreas Roodt; Alfred Muller

doi:10.1107/S1600536806012955

Carbonyl(cyclohexyldiphenylphosphine)(8-hydroxyquinolinato)rhodium(I)

J. Marthinus Janse Van Rensburg, Andreas Roodt, Alfred Muller

University of The Free State

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The molecules of the title compound, [Rh(C₉H₆NO) (C₁₈H₂₁P)(CO)], pack with the H atoms of the phenyl and cyclohexyl rings at distances of 2.80-2.85 from the adjacent oxine ligand plane. The effective cone angle (Θ_E) for the phosphine ligand is 151°. The bidentate oxine ligand has a bite angle of 79.41(9)° and the Rh - P bond length is 2.2798(8).

Original language	English
Pages (from-to)	m1040-m1042
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	5
DOIs	https://doi.org/10.1107/S1600536806012955
Publication status	Published - May 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Carbonyl(cyclohexyldiphenylphosphine)(8-hydroxyquinolinato)rhodium(I)",

abstract = "The molecules of the title compound, [Rh(C9H6NO) (C18H21P)(CO)], pack with the H atoms of the phenyl and cyclohexyl rings at distances of 2.80-2.85 from the adjacent oxine ligand plane. The effective cone angle (ΘE) for the phosphine ligand is 151°. The bidentate oxine ligand has a bite angle of 79.41(9)° and the Rh - P bond length is 2.2798(8).",

author = "{Janse Van Rensburg}, {J. Marthinus} and Andreas Roodt and Alfred Muller",

year = "2006",

month = may,

doi = "10.1107/S1600536806012955",

language = "English",

volume = "62",

pages = "m1040--m1042",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Carbonyl(cyclohexyldiphenylphosphine)(8-hydroxyquinolinato)rhodium(I)

AU - Janse Van Rensburg, J. Marthinus

AU - Roodt, Andreas

AU - Muller, Alfred

PY - 2006/5

Y1 - 2006/5

N2 - The molecules of the title compound, [Rh(C9H6NO) (C18H21P)(CO)], pack with the H atoms of the phenyl and cyclohexyl rings at distances of 2.80-2.85 from the adjacent oxine ligand plane. The effective cone angle (ΘE) for the phosphine ligand is 151°. The bidentate oxine ligand has a bite angle of 79.41(9)° and the Rh - P bond length is 2.2798(8).

AB - The molecules of the title compound, [Rh(C9H6NO) (C18H21P)(CO)], pack with the H atoms of the phenyl and cyclohexyl rings at distances of 2.80-2.85 from the adjacent oxine ligand plane. The effective cone angle (ΘE) for the phosphine ligand is 151°. The bidentate oxine ligand has a bite angle of 79.41(9)° and the Rh - P bond length is 2.2798(8).

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U2 - 10.1107/S1600536806012955

DO - 10.1107/S1600536806012955

M3 - Article

AN - SCOPUS:33744523599

SN - 1600-5368

VL - 62

SP - m1040-m1042

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Carbonyl(cyclohexyldiphenylphosphine)(8-hydroxyquinolinato)rhodium(I)

Abstract

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