Carbonyl(8-hydroxyquinolinato)[tris(2,4-ditert-butylphenyl)phosphite] rhodium(I) acetone hemisolvate

J. Marthinus Janse Van Rensburg; Andreas Roodt; Alfred Muller

doi:10.1107/S1600536806040189

Carbonyl(8-hydroxyquinolinato)[tris(2,4-ditert-butylphenyl)phosphite] rhodium(I) acetone hemisolvate

J. Marthinus Janse Van Rensburg, Andreas Roodt, Alfred Muller

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Molecules of the title compound, [Rh(C₉H₆NO)-{(C ₁₄H₂₁O)₃P}(CO)·-0.5(CH₃) ₂CO, where (C₉H₆NO) = 8-hydroxyquinolinato and {(C₁₄H₂₁O)₃P} = tris(2,4-di-tert-butylphenyl) phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand π-stacking distance of 3.312 (1) Å. The effective cone angle (⊖_E) for the phosphite ligand is 192°. The bidentate oxine ligand has a bite angle of 81.00 (8)° and the Rh - P bond length is 2.1819 (6) Å.

Original language	English
Pages (from-to)	m2978-m2980
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	11
DOIs	https://doi.org/10.1107/S1600536806040189
Publication status	Published - Nov 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{066952fafd1c47379399edd853ee42e5,

title = "Carbonyl(8-hydroxyquinolinato)[tris(2,4-ditert-butylphenyl)phosphite] rhodium(I) acetone hemisolvate",

abstract = "Molecules of the title compound, [Rh(C9H6NO)-{(C 14H21O)3P}(CO)·-0.5(CH3) 2CO, where (C9H6NO) = 8-hydroxyquinolinato and {(C14H21O)3P} = tris(2,4-di-tert-butylphenyl) phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand π-stacking distance of 3.312 (1) {\AA}. The effective cone angle (⊖E) for the phosphite ligand is 192°. The bidentate oxine ligand has a bite angle of 81.00 (8)° and the Rh - P bond length is 2.1819 (6) {\AA}.",

author = "{Janse Van Rensburg}, {J. Marthinus} and Andreas Roodt and Alfred Muller",

year = "2006",

month = nov,

doi = "10.1107/S1600536806040189",

language = "English",

volume = "62",

pages = "m2978--m2980",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

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TY - JOUR

T1 - Carbonyl(8-hydroxyquinolinato)[tris(2,4-ditert-butylphenyl)phosphite] rhodium(I) acetone hemisolvate

AU - Janse Van Rensburg, J. Marthinus

AU - Roodt, Andreas

AU - Muller, Alfred

PY - 2006/11

Y1 - 2006/11

N2 - Molecules of the title compound, [Rh(C9H6NO)-{(C 14H21O)3P}(CO)·-0.5(CH3) 2CO, where (C9H6NO) = 8-hydroxyquinolinato and {(C14H21O)3P} = tris(2,4-di-tert-butylphenyl) phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand π-stacking distance of 3.312 (1) Å. The effective cone angle (⊖E) for the phosphite ligand is 192°. The bidentate oxine ligand has a bite angle of 81.00 (8)° and the Rh - P bond length is 2.1819 (6) Å.

AB - Molecules of the title compound, [Rh(C9H6NO)-{(C 14H21O)3P}(CO)·-0.5(CH3) 2CO, where (C9H6NO) = 8-hydroxyquinolinato and {(C14H21O)3P} = tris(2,4-di-tert-butylphenyl) phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand π-stacking distance of 3.312 (1) Å. The effective cone angle (⊖E) for the phosphite ligand is 192°. The bidentate oxine ligand has a bite angle of 81.00 (8)° and the Rh - P bond length is 2.1819 (6) Å.

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U2 - 10.1107/S1600536806040189

DO - 10.1107/S1600536806040189

M3 - Article

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Carbonyl(8-hydroxyquinolinato)[tris(2,4-ditert-butylphenyl)phosphite] rhodium(I) acetone hemisolvate

Abstract

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