Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

J. Van Marthinus Janse Rensburg; Andreas Roodt; Alfred Muller; Reinout Meijboom

doi:10.1107/S1600536805038912

Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

J. Van Marthinus Janse Rensburg, Andreas Roodt, Alfred Muller, Reinout Meijboom

University of The Free State

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The molecules of the title compound, [Rh(C₉H₆NO) (C₂₁H₂₁O₃P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (Θ_E) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

Original language	English
Pages (from-to)	m2743-m2745
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	12
DOIs	https://doi.org/10.1107/S1600536805038912
Publication status	Published - 1 Dec 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536805038912

Cite this

@article{f8221c800ca24c42a64b3df0f9484307,

title = "Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)",

abstract = "The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) {\AA}. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) {\AA}.",

author = "\{Van Marthinus Janse Rensburg\}, J. and Andreas Roodt and Alfred Muller and Reinout Meijboom",

year = "2005",

month = dec,

day = "1",

doi = "10.1107/S1600536805038912",

language = "English",

volume = "61",

pages = "m2743--m2745",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

AU - Van Marthinus Janse Rensburg, J.

AU - Roodt, Andreas

AU - Muller, Alfred

AU - Meijboom, Reinout

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

AB - The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

UR - https://www.scopus.com/pages/publications/33644500495

U2 - 10.1107/S1600536805038912

DO - 10.1107/S1600536805038912

M3 - Article

AN - SCOPUS:33644500495

SN - 1600-5368

VL - 61

SP - m2743-m2745

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this