Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

J. Van Marthinus Janse Rensburg; Andreas Roodt; Alfred Muller; Reinout Meijboom

doi:10.1107/S1600536805038912

Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

J. Van Marthinus Janse Rensburg, Andreas Roodt, Alfred Muller, Reinout Meijboom

University of The Free State

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The molecules of the title compound, [Rh(C₉H₆NO) (C₂₁H₂₁O₃P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (Θ_E) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

Original language	English
Pages (from-to)	m2743-m2745
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	12
DOIs	https://doi.org/10.1107/S1600536805038912
Publication status	Published - 1 Dec 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536805038912

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title = "Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)",

abstract = "The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) {\AA}. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) {\AA}.",

author = "{Van Marthinus Janse Rensburg}, J. and Andreas Roodt and Alfred Muller and Reinout Meijboom",

year = "2005",

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language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

AU - Van Marthinus Janse Rensburg, J.

AU - Roodt, Andreas

AU - Muller, Alfred

AU - Meijboom, Reinout

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

AB - The molecules of the title compound, [Rh(C9H6NO) (C21H21O3P)(CO)], pack in a 'tail-to-tail' fashion, with a πstacking distance of 3.500 (1) Å. The effective cone angle (ΘE) for the phosphite ligand is 168°. The bidentate oxine ligand has a bite angle of 81.27 (11)° and the Rh-P bond distance is 2.189 (1) Å.

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U2 - 10.1107/S1600536805038912

DO - 10.1107/S1600536805038912

M3 - Article

AN - SCOPUS:33644500495

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SP - m2743-m2745

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Carbonyl(8-hydroxyquinolinato)[tris(2-methylphenyl) phosphite]rhodium(I)

Abstract

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